4-((E)-{2-[N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)carboximido­yl]benzyl­idene}amino)-1,5-dimethyl-2-phenyl-2,3-dihydro-1H-pyrazol-3-one

The title compound, C(30)H(28)N(6)O(2), is a symmetric diimine derived from ortho-dibenzaldehyde. Both C=N bonds are (E)-configured. The terminal N-bonded phenyl groups adopt staggered conformations relative to their respective parent heterocycles, the relevant least-squares planes inter­sect at ang...

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Detalles Bibliográficos
Autores principales: Potgieter, Kim, Hosten, Eric, Gerber, Thomas, Betz, Richard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201528/
https://www.ncbi.nlm.nih.gov/pubmed/22064831
http://dx.doi.org/10.1107/S1600536811039158
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author Potgieter, Kim
Hosten, Eric
Gerber, Thomas
Betz, Richard
author_facet Potgieter, Kim
Hosten, Eric
Gerber, Thomas
Betz, Richard
author_sort Potgieter, Kim
collection PubMed
description The title compound, C(30)H(28)N(6)O(2), is a symmetric diimine derived from ortho-dibenzaldehyde. Both C=N bonds are (E)-configured. The terminal N-bonded phenyl groups adopt staggered conformations relative to their respective parent heterocycles, the relevant least-squares planes inter­sect at angles of 32.35 (11) and 38.59 (10)°. In the crystal, C—H⋯O contacts connect the mol­ecules into chains along the b axis and give rise to a C (1) (1)(14)C (1) (1)(14) and a R (2) (2)(12) pattern on different levels of graph-set analysis. The shortest inter­centroid distance between two centroids was found at 4.2074 (11) Å between the two five-membered heterocycles.
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spelling pubmed-32015282011-11-06 4-((E)-{2-[N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)carboximido­yl]benzyl­idene}amino)-1,5-dimethyl-2-phenyl-2,3-dihydro-1H-pyrazol-3-one Potgieter, Kim Hosten, Eric Gerber, Thomas Betz, Richard Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(30)H(28)N(6)O(2), is a symmetric diimine derived from ortho-dibenzaldehyde. Both C=N bonds are (E)-configured. The terminal N-bonded phenyl groups adopt staggered conformations relative to their respective parent heterocycles, the relevant least-squares planes inter­sect at angles of 32.35 (11) and 38.59 (10)°. In the crystal, C—H⋯O contacts connect the mol­ecules into chains along the b axis and give rise to a C (1) (1)(14)C (1) (1)(14) and a R (2) (2)(12) pattern on different levels of graph-set analysis. The shortest inter­centroid distance between two centroids was found at 4.2074 (11) Å between the two five-membered heterocycles. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201528/ /pubmed/22064831 http://dx.doi.org/10.1107/S1600536811039158 Text en © Potgieter et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Potgieter, Kim
Hosten, Eric
Gerber, Thomas
Betz, Richard
4-((E)-{2-[N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)carboximido­yl]benzyl­idene}amino)-1,5-dimethyl-2-phenyl-2,3-dihydro-1H-pyrazol-3-one
title 4-((E)-{2-[N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)carboximido­yl]benzyl­idene}amino)-1,5-dimethyl-2-phenyl-2,3-dihydro-1H-pyrazol-3-one
title_full 4-((E)-{2-[N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)carboximido­yl]benzyl­idene}amino)-1,5-dimethyl-2-phenyl-2,3-dihydro-1H-pyrazol-3-one
title_fullStr 4-((E)-{2-[N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)carboximido­yl]benzyl­idene}amino)-1,5-dimethyl-2-phenyl-2,3-dihydro-1H-pyrazol-3-one
title_full_unstemmed 4-((E)-{2-[N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)carboximido­yl]benzyl­idene}amino)-1,5-dimethyl-2-phenyl-2,3-dihydro-1H-pyrazol-3-one
title_short 4-((E)-{2-[N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)carboximido­yl]benzyl­idene}amino)-1,5-dimethyl-2-phenyl-2,3-dihydro-1H-pyrazol-3-one
title_sort 4-((e)-{2-[n-(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1h-pyrazol-4-yl)carboximido­yl]benzyl­idene}amino)-1,5-dimethyl-2-phenyl-2,3-dihydro-1h-pyrazol-3-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201528/
https://www.ncbi.nlm.nih.gov/pubmed/22064831
http://dx.doi.org/10.1107/S1600536811039158
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