4-[Bis(3-phenyl-1H-pyrazol-1-yl)meth­yl]benzene-1,2-diol

The title compound, C(25)H(20)N(4)O(2), is a ditopic ortho-hydro­quinone-based bis­(pyrazol-1-yl)methane ligand. The dihedral angles between the planes of the pyrazole rings and their attached phenyl rings are 17.4 (3) and 5.9 (4)°. The pyrazole rings make a dihedral angle of 87.84 (16)°. One of the...

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Detalles Bibliográficos
Autores principales: Blasberg, Florian, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201530/
https://www.ncbi.nlm.nih.gov/pubmed/22058803
http://dx.doi.org/10.1107/S1600536811037949
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author Blasberg, Florian
Lerner, Hans-Wolfram
Bolte, Michael
author_facet Blasberg, Florian
Lerner, Hans-Wolfram
Bolte, Michael
author_sort Blasberg, Florian
collection PubMed
description The title compound, C(25)H(20)N(4)O(2), is a ditopic ortho-hydro­quinone-based bis­(pyrazol-1-yl)methane ligand. The dihedral angles between the planes of the pyrazole rings and their attached phenyl rings are 17.4 (3) and 5.9 (4)°. The pyrazole rings make a dihedral angle of 87.84 (16)°. One of the two hy­droxy groups forms an intra­molecular hydrogen bond to the other hy­droxy group, whereas the second is involved in an inter­molecular O—H⋯N hydrogen bond. As a result of these inter­molecular hydrogen bonds, helical chains running along the b axis are formed.
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spelling pubmed-32015302011-11-06 4-[Bis(3-phenyl-1H-pyrazol-1-yl)meth­yl]benzene-1,2-diol Blasberg, Florian Lerner, Hans-Wolfram Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(25)H(20)N(4)O(2), is a ditopic ortho-hydro­quinone-based bis­(pyrazol-1-yl)methane ligand. The dihedral angles between the planes of the pyrazole rings and their attached phenyl rings are 17.4 (3) and 5.9 (4)°. The pyrazole rings make a dihedral angle of 87.84 (16)°. One of the two hy­droxy groups forms an intra­molecular hydrogen bond to the other hy­droxy group, whereas the second is involved in an inter­molecular O—H⋯N hydrogen bond. As a result of these inter­molecular hydrogen bonds, helical chains running along the b axis are formed. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201530/ /pubmed/22058803 http://dx.doi.org/10.1107/S1600536811037949 Text en © Blasberg et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Blasberg, Florian
Lerner, Hans-Wolfram
Bolte, Michael
4-[Bis(3-phenyl-1H-pyrazol-1-yl)meth­yl]benzene-1,2-diol
title 4-[Bis(3-phenyl-1H-pyrazol-1-yl)meth­yl]benzene-1,2-diol
title_full 4-[Bis(3-phenyl-1H-pyrazol-1-yl)meth­yl]benzene-1,2-diol
title_fullStr 4-[Bis(3-phenyl-1H-pyrazol-1-yl)meth­yl]benzene-1,2-diol
title_full_unstemmed 4-[Bis(3-phenyl-1H-pyrazol-1-yl)meth­yl]benzene-1,2-diol
title_short 4-[Bis(3-phenyl-1H-pyrazol-1-yl)meth­yl]benzene-1,2-diol
title_sort 4-[bis(3-phenyl-1h-pyrazol-1-yl)meth­yl]benzene-1,2-diol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201530/
https://www.ncbi.nlm.nih.gov/pubmed/22058803
http://dx.doi.org/10.1107/S1600536811037949
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