4-(4-Chloro­phen­yl)-8-methyl-2-oxo-1,2,5,6,7,8-hexa­hydro­quinoline-3-carbonitrile

The six-membered N-heterocyclic ring of the title compound, C(17)H(15)ClN(2)O, is fused with a methyl-substituted cyclo­hexene ring. The approximately planar nitro­gen-bearing ring (r.m.s. deviation 0.019 Å) is aromatic, and the N atom shows a trigonal–planar coordination; its benzene substituent is...

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Autores principales: Asiri, Abdullah M., Al-Youbi, Abdulrahman O., Faidallah, Hassan M., Badahdah, Khadija O., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201532/
https://www.ncbi.nlm.nih.gov/pubmed/22064998
http://dx.doi.org/10.1107/S1600536811036142
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author Asiri, Abdullah M.
Al-Youbi, Abdulrahman O.
Faidallah, Hassan M.
Badahdah, Khadija O.
Ng, Seik Weng
author_facet Asiri, Abdullah M.
Al-Youbi, Abdulrahman O.
Faidallah, Hassan M.
Badahdah, Khadija O.
Ng, Seik Weng
author_sort Asiri, Abdullah M.
collection PubMed
description The six-membered N-heterocyclic ring of the title compound, C(17)H(15)ClN(2)O, is fused with a methyl-substituted cyclo­hexene ring. The approximately planar nitro­gen-bearing ring (r.m.s. deviation 0.019 Å) is aromatic, and the N atom shows a trigonal–planar coordination; its benzene substituent is aligned at 77.1 (1) °. The cyclo­hexene ring adopts a half-chair conformation. In the crystal, inversion-related mol­ecules are linked by pairs of N—H⋯O hydrogen bonds, generating dimers.
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spelling pubmed-32015322011-11-06 4-(4-Chloro­phen­yl)-8-methyl-2-oxo-1,2,5,6,7,8-hexa­hydro­quinoline-3-carbonitrile Asiri, Abdullah M. Al-Youbi, Abdulrahman O. Faidallah, Hassan M. Badahdah, Khadija O. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The six-membered N-heterocyclic ring of the title compound, C(17)H(15)ClN(2)O, is fused with a methyl-substituted cyclo­hexene ring. The approximately planar nitro­gen-bearing ring (r.m.s. deviation 0.019 Å) is aromatic, and the N atom shows a trigonal–planar coordination; its benzene substituent is aligned at 77.1 (1) °. The cyclo­hexene ring adopts a half-chair conformation. In the crystal, inversion-related mol­ecules are linked by pairs of N—H⋯O hydrogen bonds, generating dimers. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201532/ /pubmed/22064998 http://dx.doi.org/10.1107/S1600536811036142 Text en © Asiri et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Asiri, Abdullah M.
Al-Youbi, Abdulrahman O.
Faidallah, Hassan M.
Badahdah, Khadija O.
Ng, Seik Weng
4-(4-Chloro­phen­yl)-8-methyl-2-oxo-1,2,5,6,7,8-hexa­hydro­quinoline-3-carbonitrile
title 4-(4-Chloro­phen­yl)-8-methyl-2-oxo-1,2,5,6,7,8-hexa­hydro­quinoline-3-carbonitrile
title_full 4-(4-Chloro­phen­yl)-8-methyl-2-oxo-1,2,5,6,7,8-hexa­hydro­quinoline-3-carbonitrile
title_fullStr 4-(4-Chloro­phen­yl)-8-methyl-2-oxo-1,2,5,6,7,8-hexa­hydro­quinoline-3-carbonitrile
title_full_unstemmed 4-(4-Chloro­phen­yl)-8-methyl-2-oxo-1,2,5,6,7,8-hexa­hydro­quinoline-3-carbonitrile
title_short 4-(4-Chloro­phen­yl)-8-methyl-2-oxo-1,2,5,6,7,8-hexa­hydro­quinoline-3-carbonitrile
title_sort 4-(4-chloro­phen­yl)-8-methyl-2-oxo-1,2,5,6,7,8-hexa­hydro­quinoline-3-carbonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201532/
https://www.ncbi.nlm.nih.gov/pubmed/22064998
http://dx.doi.org/10.1107/S1600536811036142
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