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(R)-2-Phenoxy-1-(4-phenyl-2-sulfanylidene-1,3-oxazolidin-3-yl)ethanone
The central 1,3-oxazolidine-2-thione ring in the title compound, C(17)H(15)NO(3)S, is approximately planar with maximum deviations of 0.036 (4) and −0.041 (5) Å for the O and methylene-C atoms, respectively. The dihedral angles formed between this plane and the two benzene rings, which lie to the s...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201535/ https://www.ncbi.nlm.nih.gov/pubmed/22065310 http://dx.doi.org/10.1107/S160053681103858X |
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author | Caracelli, Ignez Coelho, Daniel C. S. Olivato, Paulo R. Correra, Thiago C. Rodrigues, Alessandro Tiekink, Edward R. T. |
author_facet | Caracelli, Ignez Coelho, Daniel C. S. Olivato, Paulo R. Correra, Thiago C. Rodrigues, Alessandro Tiekink, Edward R. T. |
author_sort | Caracelli, Ignez |
collection | PubMed |
description | The central 1,3-oxazolidine-2-thione ring in the title compound, C(17)H(15)NO(3)S, is approximately planar with maximum deviations of 0.036 (4) and −0.041 (5) Å for the O and methylene-C atoms, respectively. The dihedral angles formed between this plane and the two benzene rings, which lie to the same side of the central plane, are 86.5 (2) [ring-bound benzene] and 50.6 (3)°. The ethan-1-one residue is also twisted out of the central plane, forming a O—C—N—C torsion angle of 151.5 (5)°. The dihedral angle formed by the benzene rings is 62.8 (2)° so that overall, the molecule has a twisted U-shape. In the crystal, molecules are linked into supramolecular arrays two molecules thick in the bc plane through C—H⋯O, C—H⋯S and C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3201535 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32015352011-11-06 (R)-2-Phenoxy-1-(4-phenyl-2-sulfanylidene-1,3-oxazolidin-3-yl)ethanone Caracelli, Ignez Coelho, Daniel C. S. Olivato, Paulo R. Correra, Thiago C. Rodrigues, Alessandro Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The central 1,3-oxazolidine-2-thione ring in the title compound, C(17)H(15)NO(3)S, is approximately planar with maximum deviations of 0.036 (4) and −0.041 (5) Å for the O and methylene-C atoms, respectively. The dihedral angles formed between this plane and the two benzene rings, which lie to the same side of the central plane, are 86.5 (2) [ring-bound benzene] and 50.6 (3)°. The ethan-1-one residue is also twisted out of the central plane, forming a O—C—N—C torsion angle of 151.5 (5)°. The dihedral angle formed by the benzene rings is 62.8 (2)° so that overall, the molecule has a twisted U-shape. In the crystal, molecules are linked into supramolecular arrays two molecules thick in the bc plane through C—H⋯O, C—H⋯S and C—H⋯π interactions. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201535/ /pubmed/22065310 http://dx.doi.org/10.1107/S160053681103858X Text en © Caracelli et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Caracelli, Ignez Coelho, Daniel C. S. Olivato, Paulo R. Correra, Thiago C. Rodrigues, Alessandro Tiekink, Edward R. T. (R)-2-Phenoxy-1-(4-phenyl-2-sulfanylidene-1,3-oxazolidin-3-yl)ethanone |
title | (R)-2-Phenoxy-1-(4-phenyl-2-sulfanylidene-1,3-oxazolidin-3-yl)ethanone |
title_full | (R)-2-Phenoxy-1-(4-phenyl-2-sulfanylidene-1,3-oxazolidin-3-yl)ethanone |
title_fullStr | (R)-2-Phenoxy-1-(4-phenyl-2-sulfanylidene-1,3-oxazolidin-3-yl)ethanone |
title_full_unstemmed | (R)-2-Phenoxy-1-(4-phenyl-2-sulfanylidene-1,3-oxazolidin-3-yl)ethanone |
title_short | (R)-2-Phenoxy-1-(4-phenyl-2-sulfanylidene-1,3-oxazolidin-3-yl)ethanone |
title_sort | (r)-2-phenoxy-1-(4-phenyl-2-sulfanylidene-1,3-oxazolidin-3-yl)ethanone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201535/ https://www.ncbi.nlm.nih.gov/pubmed/22065310 http://dx.doi.org/10.1107/S160053681103858X |
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