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(R)-2-Phen­oxy-1-(4-phenyl-2-sulfan­ylidene-1,3-oxazolidin-3-yl)ethanone

The central 1,3-oxazolidine-2-thione ring in the title compound, C(17)H(15)NO(3)S, is approximately planar with maximum deviations of 0.036 (4) and −0.041 (5) Å for the O and methyl­ene-C atoms, respectively. The dihedral angles formed between this plane and the two benzene rings, which lie to the s...

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Autores principales: Caracelli, Ignez, Coelho, Daniel C. S., Olivato, Paulo R., Correra, Thiago C., Rodrigues, Alessandro, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201535/
https://www.ncbi.nlm.nih.gov/pubmed/22065310
http://dx.doi.org/10.1107/S160053681103858X
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author Caracelli, Ignez
Coelho, Daniel C. S.
Olivato, Paulo R.
Correra, Thiago C.
Rodrigues, Alessandro
Tiekink, Edward R. T.
author_facet Caracelli, Ignez
Coelho, Daniel C. S.
Olivato, Paulo R.
Correra, Thiago C.
Rodrigues, Alessandro
Tiekink, Edward R. T.
author_sort Caracelli, Ignez
collection PubMed
description The central 1,3-oxazolidine-2-thione ring in the title compound, C(17)H(15)NO(3)S, is approximately planar with maximum deviations of 0.036 (4) and −0.041 (5) Å for the O and methyl­ene-C atoms, respectively. The dihedral angles formed between this plane and the two benzene rings, which lie to the same side of the central plane, are 86.5 (2) [ring-bound benzene] and 50.6 (3)°. The ethan-1-one residue is also twisted out of the central plane, forming a O—C—N—C torsion angle of 151.5 (5)°. The dihedral angle formed by the benzene rings is 62.8 (2)° so that overall, the mol­ecule has a twisted U-shape. In the crystal, mol­ecules are linked into supra­molecular arrays two mol­ecules thick in the bc plane through C—H⋯O, C—H⋯S and C—H⋯π inter­actions.
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spelling pubmed-32015352011-11-06 (R)-2-Phen­oxy-1-(4-phenyl-2-sulfan­ylidene-1,3-oxazolidin-3-yl)ethanone Caracelli, Ignez Coelho, Daniel C. S. Olivato, Paulo R. Correra, Thiago C. Rodrigues, Alessandro Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The central 1,3-oxazolidine-2-thione ring in the title compound, C(17)H(15)NO(3)S, is approximately planar with maximum deviations of 0.036 (4) and −0.041 (5) Å for the O and methyl­ene-C atoms, respectively. The dihedral angles formed between this plane and the two benzene rings, which lie to the same side of the central plane, are 86.5 (2) [ring-bound benzene] and 50.6 (3)°. The ethan-1-one residue is also twisted out of the central plane, forming a O—C—N—C torsion angle of 151.5 (5)°. The dihedral angle formed by the benzene rings is 62.8 (2)° so that overall, the mol­ecule has a twisted U-shape. In the crystal, mol­ecules are linked into supra­molecular arrays two mol­ecules thick in the bc plane through C—H⋯O, C—H⋯S and C—H⋯π inter­actions. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201535/ /pubmed/22065310 http://dx.doi.org/10.1107/S160053681103858X Text en © Caracelli et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Caracelli, Ignez
Coelho, Daniel C. S.
Olivato, Paulo R.
Correra, Thiago C.
Rodrigues, Alessandro
Tiekink, Edward R. T.
(R)-2-Phen­oxy-1-(4-phenyl-2-sulfan­ylidene-1,3-oxazolidin-3-yl)ethanone
title (R)-2-Phen­oxy-1-(4-phenyl-2-sulfan­ylidene-1,3-oxazolidin-3-yl)ethanone
title_full (R)-2-Phen­oxy-1-(4-phenyl-2-sulfan­ylidene-1,3-oxazolidin-3-yl)ethanone
title_fullStr (R)-2-Phen­oxy-1-(4-phenyl-2-sulfan­ylidene-1,3-oxazolidin-3-yl)ethanone
title_full_unstemmed (R)-2-Phen­oxy-1-(4-phenyl-2-sulfan­ylidene-1,3-oxazolidin-3-yl)ethanone
title_short (R)-2-Phen­oxy-1-(4-phenyl-2-sulfan­ylidene-1,3-oxazolidin-3-yl)ethanone
title_sort (r)-2-phen­oxy-1-(4-phenyl-2-sulfan­ylidene-1,3-oxazolidin-3-yl)ethanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201535/
https://www.ncbi.nlm.nih.gov/pubmed/22065310
http://dx.doi.org/10.1107/S160053681103858X
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