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Poly[(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)(μ(3)-5-hy­droxy­isophthalato-κ(4) O (1):O (3),O (3′):O (3′))cadmium]

In the title compound, [Cd(C(8)H(4)O(5))(C(12)H(12)N(2))], the Cd(II) cation is coordinated by three 5-hy­droxy­isophthalate anions and one 5,5′-bimethyl-2,2′-bipyridine ligand in a distorted CdO(4)N(2) octa­hedral geometry. The 5-hy­droxy­isophthalate anions bridge the Cd cations, forming a two-dim...

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Detalles Bibliográficos
Autores principales: Hu, Xi-Ying, Zhai, Wen-Hang, Ma, Ning, Yang, Guang-Rui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201542/
https://www.ncbi.nlm.nih.gov/pubmed/22065692
http://dx.doi.org/10.1107/S1600536811035975
Descripción
Sumario:In the title compound, [Cd(C(8)H(4)O(5))(C(12)H(12)N(2))], the Cd(II) cation is coordinated by three 5-hy­droxy­isophthalate anions and one 5,5′-bimethyl-2,2′-bipyridine ligand in a distorted CdO(4)N(2) octa­hedral geometry. The 5-hy­droxy­isophthalate anions bridge the Cd cations, forming a two-dimensional polymeric complex parallel to (100). In the complex, the hy­droxy group is linked to the uncoordinated carb­oxy-O atom via an O—H⋯O hydrogen bond. Weak C—H⋯O hydrogen bonds are also present in the crystal structure. One of the methyl groups is disordered over two positions in a 0.536 (11):0.464 (11) ratio.