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Poly[(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)(μ(3)-5-hydroxyisophthalato-κ(4) O (1):O (3),O (3′):O (3′))cadmium]
In the title compound, [Cd(C(8)H(4)O(5))(C(12)H(12)N(2))], the Cd(II) cation is coordinated by three 5-hydroxyisophthalate anions and one 5,5′-bimethyl-2,2′-bipyridine ligand in a distorted CdO(4)N(2) octahedral geometry. The 5-hydroxyisophthalate anions bridge the Cd cations, forming a two-dim...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201542/ https://www.ncbi.nlm.nih.gov/pubmed/22065692 http://dx.doi.org/10.1107/S1600536811035975 |
Sumario: | In the title compound, [Cd(C(8)H(4)O(5))(C(12)H(12)N(2))], the Cd(II) cation is coordinated by three 5-hydroxyisophthalate anions and one 5,5′-bimethyl-2,2′-bipyridine ligand in a distorted CdO(4)N(2) octahedral geometry. The 5-hydroxyisophthalate anions bridge the Cd cations, forming a two-dimensional polymeric complex parallel to (100). In the complex, the hydroxy group is linked to the uncoordinated carboxy-O atom via an O—H⋯O hydrogen bond. Weak C—H⋯O hydrogen bonds are also present in the crystal structure. One of the methyl groups is disordered over two positions in a 0.536 (11):0.464 (11) ratio. |
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