Cargando…
Poly[(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)(μ(3)-5-hydroxyisophthalato-κ(4) O (1):O (3),O (3′):O (3′))cadmium]
In the title compound, [Cd(C(8)H(4)O(5))(C(12)H(12)N(2))], the Cd(II) cation is coordinated by three 5-hydroxyisophthalate anions and one 5,5′-bimethyl-2,2′-bipyridine ligand in a distorted CdO(4)N(2) octahedral geometry. The 5-hydroxyisophthalate anions bridge the Cd cations, forming a two-dim...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201542/ https://www.ncbi.nlm.nih.gov/pubmed/22065692 http://dx.doi.org/10.1107/S1600536811035975 |
| _version_ | 1782214898538774528 |
|---|---|
| author | Hu, Xi-Ying Zhai, Wen-Hang Ma, Ning Yang, Guang-Rui |
| author_facet | Hu, Xi-Ying Zhai, Wen-Hang Ma, Ning Yang, Guang-Rui |
| author_sort | Hu, Xi-Ying |
| collection | PubMed |
| description | In the title compound, [Cd(C(8)H(4)O(5))(C(12)H(12)N(2))], the Cd(II) cation is coordinated by three 5-hydroxyisophthalate anions and one 5,5′-bimethyl-2,2′-bipyridine ligand in a distorted CdO(4)N(2) octahedral geometry. The 5-hydroxyisophthalate anions bridge the Cd cations, forming a two-dimensional polymeric complex parallel to (100). In the complex, the hydroxy group is linked to the uncoordinated carboxy-O atom via an O—H⋯O hydrogen bond. Weak C—H⋯O hydrogen bonds are also present in the crystal structure. One of the methyl groups is disordered over two positions in a 0.536 (11):0.464 (11) ratio. |
| format | Online Article Text |
| id | pubmed-3201542 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32015422011-11-06 Poly[(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)(μ(3)-5-hydroxyisophthalato-κ(4) O (1):O (3),O (3′):O (3′))cadmium] Hu, Xi-Ying Zhai, Wen-Hang Ma, Ning Yang, Guang-Rui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(8)H(4)O(5))(C(12)H(12)N(2))], the Cd(II) cation is coordinated by three 5-hydroxyisophthalate anions and one 5,5′-bimethyl-2,2′-bipyridine ligand in a distorted CdO(4)N(2) octahedral geometry. The 5-hydroxyisophthalate anions bridge the Cd cations, forming a two-dimensional polymeric complex parallel to (100). In the complex, the hydroxy group is linked to the uncoordinated carboxy-O atom via an O—H⋯O hydrogen bond. Weak C—H⋯O hydrogen bonds are also present in the crystal structure. One of the methyl groups is disordered over two positions in a 0.536 (11):0.464 (11) ratio. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201542/ /pubmed/22065692 http://dx.doi.org/10.1107/S1600536811035975 Text en © Hu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Hu, Xi-Ying Zhai, Wen-Hang Ma, Ning Yang, Guang-Rui Poly[(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)(μ(3)-5-hydroxyisophthalato-κ(4) O (1):O (3),O (3′):O (3′))cadmium] |
| title | Poly[(5,5′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)(μ(3)-5-hydroxyisophthalato-κ(4)
O
(1):O
(3),O
(3′):O
(3′))cadmium] |
| title_full | Poly[(5,5′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)(μ(3)-5-hydroxyisophthalato-κ(4)
O
(1):O
(3),O
(3′):O
(3′))cadmium] |
| title_fullStr | Poly[(5,5′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)(μ(3)-5-hydroxyisophthalato-κ(4)
O
(1):O
(3),O
(3′):O
(3′))cadmium] |
| title_full_unstemmed | Poly[(5,5′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)(μ(3)-5-hydroxyisophthalato-κ(4)
O
(1):O
(3),O
(3′):O
(3′))cadmium] |
| title_short | Poly[(5,5′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)(μ(3)-5-hydroxyisophthalato-κ(4)
O
(1):O
(3),O
(3′):O
(3′))cadmium] |
| title_sort | poly[(5,5′-dimethyl-2,2′-bipyridine-κ(2)
n,n′)(μ(3)-5-hydroxyisophthalato-κ(4)
o
(1):o
(3),o
(3′):o
(3′))cadmium] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201542/ https://www.ncbi.nlm.nih.gov/pubmed/22065692 http://dx.doi.org/10.1107/S1600536811035975 |
| work_keys_str_mv | AT huxiying poly55dimethyl22bipyridinek2nnm35hydroxyisophthalatok4o1o3o3o3cadmium AT zhaiwenhang poly55dimethyl22bipyridinek2nnm35hydroxyisophthalatok4o1o3o3o3cadmium AT maning poly55dimethyl22bipyridinek2nnm35hydroxyisophthalatok4o1o3o3o3cadmium AT yangguangrui poly55dimethyl22bipyridinek2nnm35hydroxyisophthalatok4o1o3o3o3cadmium |