Cargando…

Bis(hydrogen l-glutamato)palladium(II)

In the title compound, [Pd(C(5)H(8)NO(4))(2)], the Pd(II) atom is coordinated by two O atoms and two N atoms of two N,O-chelating hydrogen l-glutatmate ligands in a square–planar geometry with the N and O atoms in a mutually trans arrangement. The complex units are embedded in a network of N—H⋯O and...

Descripción completa

Detalles Bibliográficos
Autores principales: Seifert, Antje, Wagner, Christoph, Merzweiler, Kurt
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201544/
https://www.ncbi.nlm.nih.gov/pubmed/22065700
http://dx.doi.org/10.1107/S1600536811035860
_version_ 1782214898997002240
author Seifert, Antje
Wagner, Christoph
Merzweiler, Kurt
author_facet Seifert, Antje
Wagner, Christoph
Merzweiler, Kurt
author_sort Seifert, Antje
collection PubMed
description In the title compound, [Pd(C(5)H(8)NO(4))(2)], the Pd(II) atom is coordinated by two O atoms and two N atoms of two N,O-chelating hydrogen l-glutatmate ligands in a square–planar geometry with the N and O atoms in a mutually trans arrangement. The complex units are embedded in a network of N—H⋯O and O—H⋯O hydrogen-bonding inter­actions that stabilize the three-dimensional crystal structure. The strongest hydrogen bonds are formed between the γ-COOH untis of adjacent glutamate ligands, leading to dimers of the type R (2) (2)(8) with O⋯O separations of 2.640 (6) Å.
format Online
Article
Text
id pubmed-3201544
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32015442011-11-06 Bis(hydrogen l-glutamato)palladium(II) Seifert, Antje Wagner, Christoph Merzweiler, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(C(5)H(8)NO(4))(2)], the Pd(II) atom is coordinated by two O atoms and two N atoms of two N,O-chelating hydrogen l-glutatmate ligands in a square–planar geometry with the N and O atoms in a mutually trans arrangement. The complex units are embedded in a network of N—H⋯O and O—H⋯O hydrogen-bonding inter­actions that stabilize the three-dimensional crystal structure. The strongest hydrogen bonds are formed between the γ-COOH untis of adjacent glutamate ligands, leading to dimers of the type R (2) (2)(8) with O⋯O separations of 2.640 (6) Å. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201544/ /pubmed/22065700 http://dx.doi.org/10.1107/S1600536811035860 Text en © Seifert et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Seifert, Antje
Wagner, Christoph
Merzweiler, Kurt
Bis(hydrogen l-glutamato)palladium(II)
title Bis(hydrogen l-glutamato)palladium(II)
title_full Bis(hydrogen l-glutamato)palladium(II)
title_fullStr Bis(hydrogen l-glutamato)palladium(II)
title_full_unstemmed Bis(hydrogen l-glutamato)palladium(II)
title_short Bis(hydrogen l-glutamato)palladium(II)
title_sort bis(hydrogen l-glutamato)palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201544/
https://www.ncbi.nlm.nih.gov/pubmed/22065700
http://dx.doi.org/10.1107/S1600536811035860
work_keys_str_mv AT seifertantje bishydrogenlglutamatopalladiumii
AT wagnerchristoph bishydrogenlglutamatopalladiumii
AT merzweilerkurt bishydrogenlglutamatopalladiumii