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Bis(hydrogen l-glutamato)palladium(II)
In the title compound, [Pd(C(5)H(8)NO(4))(2)], the Pd(II) atom is coordinated by two O atoms and two N atoms of two N,O-chelating hydrogen l-glutatmate ligands in a square–planar geometry with the N and O atoms in a mutually trans arrangement. The complex units are embedded in a network of N—H⋯O and...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201544/ https://www.ncbi.nlm.nih.gov/pubmed/22065700 http://dx.doi.org/10.1107/S1600536811035860 |
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author | Seifert, Antje Wagner, Christoph Merzweiler, Kurt |
author_facet | Seifert, Antje Wagner, Christoph Merzweiler, Kurt |
author_sort | Seifert, Antje |
collection | PubMed |
description | In the title compound, [Pd(C(5)H(8)NO(4))(2)], the Pd(II) atom is coordinated by two O atoms and two N atoms of two N,O-chelating hydrogen l-glutatmate ligands in a square–planar geometry with the N and O atoms in a mutually trans arrangement. The complex units are embedded in a network of N—H⋯O and O—H⋯O hydrogen-bonding interactions that stabilize the three-dimensional crystal structure. The strongest hydrogen bonds are formed between the γ-COOH untis of adjacent glutamate ligands, leading to dimers of the type R (2) (2)(8) with O⋯O separations of 2.640 (6) Å. |
format | Online Article Text |
id | pubmed-3201544 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32015442011-11-06 Bis(hydrogen l-glutamato)palladium(II) Seifert, Antje Wagner, Christoph Merzweiler, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(C(5)H(8)NO(4))(2)], the Pd(II) atom is coordinated by two O atoms and two N atoms of two N,O-chelating hydrogen l-glutatmate ligands in a square–planar geometry with the N and O atoms in a mutually trans arrangement. The complex units are embedded in a network of N—H⋯O and O—H⋯O hydrogen-bonding interactions that stabilize the three-dimensional crystal structure. The strongest hydrogen bonds are formed between the γ-COOH untis of adjacent glutamate ligands, leading to dimers of the type R (2) (2)(8) with O⋯O separations of 2.640 (6) Å. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201544/ /pubmed/22065700 http://dx.doi.org/10.1107/S1600536811035860 Text en © Seifert et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Seifert, Antje Wagner, Christoph Merzweiler, Kurt Bis(hydrogen l-glutamato)palladium(II) |
title | Bis(hydrogen l-glutamato)palladium(II) |
title_full | Bis(hydrogen l-glutamato)palladium(II) |
title_fullStr | Bis(hydrogen l-glutamato)palladium(II) |
title_full_unstemmed | Bis(hydrogen l-glutamato)palladium(II) |
title_short | Bis(hydrogen l-glutamato)palladium(II) |
title_sort | bis(hydrogen l-glutamato)palladium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201544/ https://www.ncbi.nlm.nih.gov/pubmed/22065700 http://dx.doi.org/10.1107/S1600536811035860 |
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