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1,1,1-Trifluoro-4-(thio­phen-2-yl)-4-[(2-{[4,4,4-trifluoro-3-oxo-1-(thio­phen-2-yl)but-1-en-1-yl]amino}­eth­yl)amino]­but-3-en-2-one

The asymmetric unit of the diamine compound, C(18)H(14)F(3)N(2)O(2)S(2), consists of two mol­ecules; the C=C double bond has a Z configuration in the C(4)H(3)S—C=C—C(=O)—C segment. The –NH—CH(2)—CH(2)—NH chain adopts a twisted U-shape. The amino group is an intra­molecular hydrogen-bond donor to the...

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Detalles Bibliográficos
Autores principales: Asiri, Abdullah M., Al-Youbi, Abdulrahman O., Faidallah, Hassan M., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201547/
https://www.ncbi.nlm.nih.gov/pubmed/22064455
http://dx.doi.org/10.1107/S1600536811036889
Descripción
Sumario:The asymmetric unit of the diamine compound, C(18)H(14)F(3)N(2)O(2)S(2), consists of two mol­ecules; the C=C double bond has a Z configuration in the C(4)H(3)S—C=C—C(=O)—C segment. The –NH—CH(2)—CH(2)—NH chain adopts a twisted U-shape. The amino group is an intra­molecular hydrogen-bond donor to the carbonyl group; the intra­molecular hydrogen bond generates a six-membered ring. In both mol­ecules, the thienyl rings are disordered over two positions; the occupancies of the major components are 0.817 (4) and 0.778 (4) in one mol­ecule and 0.960 (4) and 0.665 (4) in the other. One of the trifluoro­methyl groups is disordered over two positions with the major component having 0.637 (8) occupancy.