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1,1,1-Trifluoro-4-(thiophen-2-yl)-4-[(2-{[4,4,4-trifluoro-3-oxo-1-(thiophen-2-yl)but-1-en-1-yl]amino}ethyl)amino]but-3-en-2-one
The asymmetric unit of the diamine compound, C(18)H(14)F(3)N(2)O(2)S(2), consists of two molecules; the C=C double bond has a Z configuration in the C(4)H(3)S—C=C—C(=O)—C segment. The –NH—CH(2)—CH(2)—NH chain adopts a twisted U-shape. The amino group is an intramolecular hydrogen-bond donor to the...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201547/ https://www.ncbi.nlm.nih.gov/pubmed/22064455 http://dx.doi.org/10.1107/S1600536811036889 |
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author | Asiri, Abdullah M. Al-Youbi, Abdulrahman O. Faidallah, Hassan M. Ng, Seik Weng |
author_facet | Asiri, Abdullah M. Al-Youbi, Abdulrahman O. Faidallah, Hassan M. Ng, Seik Weng |
author_sort | Asiri, Abdullah M. |
collection | PubMed |
description | The asymmetric unit of the diamine compound, C(18)H(14)F(3)N(2)O(2)S(2), consists of two molecules; the C=C double bond has a Z configuration in the C(4)H(3)S—C=C—C(=O)—C segment. The –NH—CH(2)—CH(2)—NH chain adopts a twisted U-shape. The amino group is an intramolecular hydrogen-bond donor to the carbonyl group; the intramolecular hydrogen bond generates a six-membered ring. In both molecules, the thienyl rings are disordered over two positions; the occupancies of the major components are 0.817 (4) and 0.778 (4) in one molecule and 0.960 (4) and 0.665 (4) in the other. One of the trifluoromethyl groups is disordered over two positions with the major component having 0.637 (8) occupancy. |
format | Online Article Text |
id | pubmed-3201547 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32015472011-11-06 1,1,1-Trifluoro-4-(thiophen-2-yl)-4-[(2-{[4,4,4-trifluoro-3-oxo-1-(thiophen-2-yl)but-1-en-1-yl]amino}ethyl)amino]but-3-en-2-one Asiri, Abdullah M. Al-Youbi, Abdulrahman O. Faidallah, Hassan M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the diamine compound, C(18)H(14)F(3)N(2)O(2)S(2), consists of two molecules; the C=C double bond has a Z configuration in the C(4)H(3)S—C=C—C(=O)—C segment. The –NH—CH(2)—CH(2)—NH chain adopts a twisted U-shape. The amino group is an intramolecular hydrogen-bond donor to the carbonyl group; the intramolecular hydrogen bond generates a six-membered ring. In both molecules, the thienyl rings are disordered over two positions; the occupancies of the major components are 0.817 (4) and 0.778 (4) in one molecule and 0.960 (4) and 0.665 (4) in the other. One of the trifluoromethyl groups is disordered over two positions with the major component having 0.637 (8) occupancy. International Union of Crystallography 2011-09-17 /pmc/articles/PMC3201547/ /pubmed/22064455 http://dx.doi.org/10.1107/S1600536811036889 Text en © Asiri et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Asiri, Abdullah M. Al-Youbi, Abdulrahman O. Faidallah, Hassan M. Ng, Seik Weng 1,1,1-Trifluoro-4-(thiophen-2-yl)-4-[(2-{[4,4,4-trifluoro-3-oxo-1-(thiophen-2-yl)but-1-en-1-yl]amino}ethyl)amino]but-3-en-2-one |
title | 1,1,1-Trifluoro-4-(thiophen-2-yl)-4-[(2-{[4,4,4-trifluoro-3-oxo-1-(thiophen-2-yl)but-1-en-1-yl]amino}ethyl)amino]but-3-en-2-one |
title_full | 1,1,1-Trifluoro-4-(thiophen-2-yl)-4-[(2-{[4,4,4-trifluoro-3-oxo-1-(thiophen-2-yl)but-1-en-1-yl]amino}ethyl)amino]but-3-en-2-one |
title_fullStr | 1,1,1-Trifluoro-4-(thiophen-2-yl)-4-[(2-{[4,4,4-trifluoro-3-oxo-1-(thiophen-2-yl)but-1-en-1-yl]amino}ethyl)amino]but-3-en-2-one |
title_full_unstemmed | 1,1,1-Trifluoro-4-(thiophen-2-yl)-4-[(2-{[4,4,4-trifluoro-3-oxo-1-(thiophen-2-yl)but-1-en-1-yl]amino}ethyl)amino]but-3-en-2-one |
title_short | 1,1,1-Trifluoro-4-(thiophen-2-yl)-4-[(2-{[4,4,4-trifluoro-3-oxo-1-(thiophen-2-yl)but-1-en-1-yl]amino}ethyl)amino]but-3-en-2-one |
title_sort | 1,1,1-trifluoro-4-(thiophen-2-yl)-4-[(2-{[4,4,4-trifluoro-3-oxo-1-(thiophen-2-yl)but-1-en-1-yl]amino}ethyl)amino]but-3-en-2-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201547/ https://www.ncbi.nlm.nih.gov/pubmed/22064455 http://dx.doi.org/10.1107/S1600536811036889 |
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