Bis(3-benzoyl-1,1-di-sec-butyl­thio­ureato-κ(2) O,S)palladium(II)

The complex mol­ecule of the title complex, [Pd(C(16)H(23)N(2)OS)(2)], is completed by crystallographic twofold symmetry with the metal atom lying on the rotation axis. The Pd(II) atom exists within a slightly distorted square-planar geometry defined by a cis-O(2)S(2) donor set. The dihedral angle f...

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Detalles Bibliográficos
Autores principales: Selvakumaran, N., Karvembu, R., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201548/
https://www.ncbi.nlm.nih.gov/pubmed/22058701
http://dx.doi.org/10.1107/S1600536811036853
Descripción
Sumario:The complex mol­ecule of the title complex, [Pd(C(16)H(23)N(2)OS)(2)], is completed by crystallographic twofold symmetry with the metal atom lying on the rotation axis. The Pd(II) atom exists within a slightly distorted square-planar geometry defined by a cis-O(2)S(2) donor set. The dihedral angle formed between the mean planes of the symmetry-related six-membered chelate rings is 12.88 (7)° and the bond lengths within the rings are indicative of significant electron delocalization. In the crystal, mol­ecules aggregate into dimers linked by four C—H⋯O inter­actions.

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