Bis(3-benzoyl-1,1-di-sec-butyl­thio­ureato-κ(2) O,S)palladium(II)

The complex mol­ecule of the title complex, [Pd(C(16)H(23)N(2)OS)(2)], is completed by crystallographic twofold symmetry with the metal atom lying on the rotation axis. The Pd(II) atom exists within a slightly distorted square-planar geometry defined by a cis-O(2)S(2) donor set. The dihedral angle f...

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Detalles Bibliográficos
Autores principales: Selvakumaran, N., Karvembu, R., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201548/
https://www.ncbi.nlm.nih.gov/pubmed/22058701
http://dx.doi.org/10.1107/S1600536811036853
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author Selvakumaran, N.
Karvembu, R.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Selvakumaran, N.
Karvembu, R.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Selvakumaran, N.
collection PubMed
description The complex mol­ecule of the title complex, [Pd(C(16)H(23)N(2)OS)(2)], is completed by crystallographic twofold symmetry with the metal atom lying on the rotation axis. The Pd(II) atom exists within a slightly distorted square-planar geometry defined by a cis-O(2)S(2) donor set. The dihedral angle formed between the mean planes of the symmetry-related six-membered chelate rings is 12.88 (7)° and the bond lengths within the rings are indicative of significant electron delocalization. In the crystal, mol­ecules aggregate into dimers linked by four C—H⋯O inter­actions.
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spelling pubmed-32015482011-11-06 Bis(3-benzoyl-1,1-di-sec-butyl­thio­ureato-κ(2) O,S)palladium(II) Selvakumaran, N. Karvembu, R. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complex mol­ecule of the title complex, [Pd(C(16)H(23)N(2)OS)(2)], is completed by crystallographic twofold symmetry with the metal atom lying on the rotation axis. The Pd(II) atom exists within a slightly distorted square-planar geometry defined by a cis-O(2)S(2) donor set. The dihedral angle formed between the mean planes of the symmetry-related six-membered chelate rings is 12.88 (7)° and the bond lengths within the rings are indicative of significant electron delocalization. In the crystal, mol­ecules aggregate into dimers linked by four C—H⋯O inter­actions. International Union of Crystallography 2011-09-17 /pmc/articles/PMC3201548/ /pubmed/22058701 http://dx.doi.org/10.1107/S1600536811036853 Text en © Selvakumaran et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Selvakumaran, N.
Karvembu, R.
Ng, Seik Weng
Tiekink, Edward R. T.
Bis(3-benzoyl-1,1-di-sec-butyl­thio­ureato-κ(2) O,S)palladium(II)
title Bis(3-benzoyl-1,1-di-sec-butyl­thio­ureato-κ(2) O,S)palladium(II)
title_full Bis(3-benzoyl-1,1-di-sec-butyl­thio­ureato-κ(2) O,S)palladium(II)
title_fullStr Bis(3-benzoyl-1,1-di-sec-butyl­thio­ureato-κ(2) O,S)palladium(II)
title_full_unstemmed Bis(3-benzoyl-1,1-di-sec-butyl­thio­ureato-κ(2) O,S)palladium(II)
title_short Bis(3-benzoyl-1,1-di-sec-butyl­thio­ureato-κ(2) O,S)palladium(II)
title_sort bis(3-benzoyl-1,1-di-sec-butyl­thio­ureato-κ(2) o,s)palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201548/
https://www.ncbi.nlm.nih.gov/pubmed/22058701
http://dx.doi.org/10.1107/S1600536811036853
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AT tiekinkedwardrt bis3benzoyl11disecbutylthioureatok2ospalladiumii

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