Dichlorido{2-[(thio­phen-2-ylmeth­yl)imino­meth­yl]pyridine-κ(2) N,N′}palladium(II)

In the title compound, [PdCl(2)(C(11)H(10)N(2)S)], the Pd(II) ion is four-coordinated in a distorted square-planar environment by two N atoms of the chelating 2-[(thio­phen-2-ylmeth­yl)imino­meth­yl]pyridine ligand and two chloride anions. The thio­phene ring is rotationally disordered over two orie...

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Detalles Bibliográficos
Autores principales: Onani, Martin O., Motswainyana, William M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201550/
https://www.ncbi.nlm.nih.gov/pubmed/22058700
http://dx.doi.org/10.1107/S1600536811037214
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author Onani, Martin O.
Motswainyana, William M.
author_facet Onani, Martin O.
Motswainyana, William M.
author_sort Onani, Martin O.
collection PubMed
description In the title compound, [PdCl(2)(C(11)H(10)N(2)S)], the Pd(II) ion is four-coordinated in a distorted square-planar environment by two N atoms of the chelating 2-[(thio­phen-2-ylmeth­yl)imino­meth­yl]pyridine ligand and two chloride anions. The thio­phene ring is rotationally disordered over two orientations in a 1:1 ratio. The crystal packing exhibits weak inter­molecular C—H⋯Cl and C—H⋯S hydrogen bonds.
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spelling pubmed-32015502011-11-06 Dichlorido{2-[(thio­phen-2-ylmeth­yl)imino­meth­yl]pyridine-κ(2) N,N′}palladium(II) Onani, Martin O. Motswainyana, William M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdCl(2)(C(11)H(10)N(2)S)], the Pd(II) ion is four-coordinated in a distorted square-planar environment by two N atoms of the chelating 2-[(thio­phen-2-ylmeth­yl)imino­meth­yl]pyridine ligand and two chloride anions. The thio­phene ring is rotationally disordered over two orientations in a 1:1 ratio. The crystal packing exhibits weak inter­molecular C—H⋯Cl and C—H⋯S hydrogen bonds. International Union of Crystallography 2011-09-17 /pmc/articles/PMC3201550/ /pubmed/22058700 http://dx.doi.org/10.1107/S1600536811037214 Text en © Onani and Motswainyana 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Onani, Martin O.
Motswainyana, William M.
Dichlorido{2-[(thio­phen-2-ylmeth­yl)imino­meth­yl]pyridine-κ(2) N,N′}palladium(II)
title Dichlorido{2-[(thio­phen-2-ylmeth­yl)imino­meth­yl]pyridine-κ(2) N,N′}palladium(II)
title_full Dichlorido{2-[(thio­phen-2-ylmeth­yl)imino­meth­yl]pyridine-κ(2) N,N′}palladium(II)
title_fullStr Dichlorido{2-[(thio­phen-2-ylmeth­yl)imino­meth­yl]pyridine-κ(2) N,N′}palladium(II)
title_full_unstemmed Dichlorido{2-[(thio­phen-2-ylmeth­yl)imino­meth­yl]pyridine-κ(2) N,N′}palladium(II)
title_short Dichlorido{2-[(thio­phen-2-ylmeth­yl)imino­meth­yl]pyridine-κ(2) N,N′}palladium(II)
title_sort dichlorido{2-[(thio­phen-2-ylmeth­yl)imino­meth­yl]pyridine-κ(2) n,n′}palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201550/
https://www.ncbi.nlm.nih.gov/pubmed/22058700
http://dx.doi.org/10.1107/S1600536811037214
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AT motswainyanawilliamm dichlorido2thiophen2ylmethyliminomethylpyridinek2nnpalladiumii

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