Hexane-1,6-diaminium bis­[3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate] methanol disolvate

In the title compound, C(6)H(18)N(2) (2+)·2C(9)H(3)Br(4)O(4) (−)·2CH(4)O, the carboxyl­ate and meth­oxy­carbonyl groups in one of the anions form dihedral angles of 71.9 (3) and 60.7 (3)°, respectively, with the aromatic ring while in the other anion these angles are 68.4 (3) and 56.8 (3)°, respecti...

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Detalles Bibliográficos
Autor principal: Li, Jian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201551/
https://www.ncbi.nlm.nih.gov/pubmed/22058736
http://dx.doi.org/10.1107/S1600536811035537
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author Li, Jian
author_facet Li, Jian
author_sort Li, Jian
collection PubMed
description In the title compound, C(6)H(18)N(2) (2+)·2C(9)H(3)Br(4)O(4) (−)·2CH(4)O, the carboxyl­ate and meth­oxy­carbonyl groups in one of the anions form dihedral angles of 71.9 (3) and 60.7 (3)°, respectively, with the aromatic ring while in the other anion these angles are 68.4 (3) and 56.8 (3)°, respectively. In the crystal, the constituent units are linked into a two-dimensional network parallel to the ab plane by N—H⋯O and O—H⋯O hydrogen bonds.
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spelling pubmed-32015512011-11-06 Hexane-1,6-diaminium bis­[3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate] methanol disolvate Li, Jian Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(18)N(2) (2+)·2C(9)H(3)Br(4)O(4) (−)·2CH(4)O, the carboxyl­ate and meth­oxy­carbonyl groups in one of the anions form dihedral angles of 71.9 (3) and 60.7 (3)°, respectively, with the aromatic ring while in the other anion these angles are 68.4 (3) and 56.8 (3)°, respectively. In the crystal, the constituent units are linked into a two-dimensional network parallel to the ab plane by N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201551/ /pubmed/22058736 http://dx.doi.org/10.1107/S1600536811035537 Text en © Jian Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Jian
Hexane-1,6-diaminium bis­[3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate] methanol disolvate
title Hexane-1,6-diaminium bis­[3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate] methanol disolvate
title_full Hexane-1,6-diaminium bis­[3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate] methanol disolvate
title_fullStr Hexane-1,6-diaminium bis­[3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate] methanol disolvate
title_full_unstemmed Hexane-1,6-diaminium bis­[3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate] methanol disolvate
title_short Hexane-1,6-diaminium bis­[3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate] methanol disolvate
title_sort hexane-1,6-diaminium bis­[3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate] methanol disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201551/
https://www.ncbi.nlm.nih.gov/pubmed/22058736
http://dx.doi.org/10.1107/S1600536811035537
work_keys_str_mv AT lijian hexane16diaminiumbis3456tetrabromo2methoxycarbonylbenzoatemethanoldisolvate

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