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2,5-Bis(pyridinium-2-yl)-3,6-bis(2-pyridyl)pyrazine bis[tetrachloridoaurate(III)]
In the title compound, (C(24)H(18)N(6))[AuCl(4)](2), the cation is located on an inversion center. Each of the two independent Au(III) ions lies on an inversion center and has a distorted square-planar geometry. In the crystal, intermolecular C—H⋯Cl hydrogen bonds, π–π interactions [centroid–centr...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201553/ https://www.ncbi.nlm.nih.gov/pubmed/22064756 http://dx.doi.org/10.1107/S1600536811036208 |
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author | Abedi, Anita Dabbaghi, Azra Amani, Vahid |
author_facet | Abedi, Anita Dabbaghi, Azra Amani, Vahid |
author_sort | Abedi, Anita |
collection | PubMed |
description | In the title compound, (C(24)H(18)N(6))[AuCl(4)](2), the cation is located on an inversion center. Each of the two independent Au(III) ions lies on an inversion center and has a distorted square-planar geometry. In the crystal, intermolecular C—H⋯Cl hydrogen bonds, π–π interactions [centroid–centroid distances = 3.5548 (16) and 3.7507 (16) Å] and Au⋯π interactions [Au⋯centroid distance = 3.6424 (10) Å] are effective in the stabilization of the structure, resulting in the formation of a supramolecular structure. Intramolecular N—H⋯N hydrogen bonds are present in the cation. |
format | Online Article Text |
id | pubmed-3201553 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32015532011-11-06 2,5-Bis(pyridinium-2-yl)-3,6-bis(2-pyridyl)pyrazine bis[tetrachloridoaurate(III)] Abedi, Anita Dabbaghi, Azra Amani, Vahid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(24)H(18)N(6))[AuCl(4)](2), the cation is located on an inversion center. Each of the two independent Au(III) ions lies on an inversion center and has a distorted square-planar geometry. In the crystal, intermolecular C—H⋯Cl hydrogen bonds, π–π interactions [centroid–centroid distances = 3.5548 (16) and 3.7507 (16) Å] and Au⋯π interactions [Au⋯centroid distance = 3.6424 (10) Å] are effective in the stabilization of the structure, resulting in the formation of a supramolecular structure. Intramolecular N—H⋯N hydrogen bonds are present in the cation. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201553/ /pubmed/22064756 http://dx.doi.org/10.1107/S1600536811036208 Text en © Abedi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Abedi, Anita Dabbaghi, Azra Amani, Vahid 2,5-Bis(pyridinium-2-yl)-3,6-bis(2-pyridyl)pyrazine bis[tetrachloridoaurate(III)] |
title | 2,5-Bis(pyridinium-2-yl)-3,6-bis(2-pyridyl)pyrazine bis[tetrachloridoaurate(III)] |
title_full | 2,5-Bis(pyridinium-2-yl)-3,6-bis(2-pyridyl)pyrazine bis[tetrachloridoaurate(III)] |
title_fullStr | 2,5-Bis(pyridinium-2-yl)-3,6-bis(2-pyridyl)pyrazine bis[tetrachloridoaurate(III)] |
title_full_unstemmed | 2,5-Bis(pyridinium-2-yl)-3,6-bis(2-pyridyl)pyrazine bis[tetrachloridoaurate(III)] |
title_short | 2,5-Bis(pyridinium-2-yl)-3,6-bis(2-pyridyl)pyrazine bis[tetrachloridoaurate(III)] |
title_sort | 2,5-bis(pyridinium-2-yl)-3,6-bis(2-pyridyl)pyrazine bis[tetrachloridoaurate(iii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201553/ https://www.ncbi.nlm.nih.gov/pubmed/22064756 http://dx.doi.org/10.1107/S1600536811036208 |
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