Bis(nitrato-κO)tetra­kis­[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one]copper(II)

In the title complex, [Cu(NO(3))(2)(C(11)H(11)N(3)O)(4)], the Cu(II) atom is situated on a centre of inversion and is coordinated by two O atoms from two nitrate anions and four N atoms from four monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands in a distorted octa­hedral geometry....

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Detalles Bibliográficos
Autores principales: Cai, Hua, Guo, Ying, Li, Jian-Gang, Wu, Yao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201555/
https://www.ncbi.nlm.nih.gov/pubmed/22064784
http://dx.doi.org/10.1107/S160053681103529X
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author Cai, Hua
Guo, Ying
Li, Jian-Gang
Wu, Yao
author_facet Cai, Hua
Guo, Ying
Li, Jian-Gang
Wu, Yao
author_sort Cai, Hua
collection PubMed
description In the title complex, [Cu(NO(3))(2)(C(11)H(11)N(3)O)(4)], the Cu(II) atom is situated on a centre of inversion and is coordinated by two O atoms from two nitrate anions and four N atoms from four monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands in a distorted octa­hedral geometry. Weak inter­molecular C—H⋯O and C—H⋯N hydrogen bonds result in a supra­molecular layer parallel to (101). These layers are connected by π–π inter­actions between the benzene rings [centroid–centroid distance = 3.891 (2) Å].
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spelling pubmed-32015552011-11-06 Bis(nitrato-κO)tetra­kis­[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one]copper(II) Cai, Hua Guo, Ying Li, Jian-Gang Wu, Yao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(NO(3))(2)(C(11)H(11)N(3)O)(4)], the Cu(II) atom is situated on a centre of inversion and is coordinated by two O atoms from two nitrate anions and four N atoms from four monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands in a distorted octa­hedral geometry. Weak inter­molecular C—H⋯O and C—H⋯N hydrogen bonds result in a supra­molecular layer parallel to (101). These layers are connected by π–π inter­actions between the benzene rings [centroid–centroid distance = 3.891 (2) Å]. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201555/ /pubmed/22064784 http://dx.doi.org/10.1107/S160053681103529X Text en © Cai et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cai, Hua
Guo, Ying
Li, Jian-Gang
Wu, Yao
Bis(nitrato-κO)tetra­kis­[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one]copper(II)
title Bis(nitrato-κO)tetra­kis­[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one]copper(II)
title_full Bis(nitrato-κO)tetra­kis­[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one]copper(II)
title_fullStr Bis(nitrato-κO)tetra­kis­[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one]copper(II)
title_full_unstemmed Bis(nitrato-κO)tetra­kis­[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one]copper(II)
title_short Bis(nitrato-κO)tetra­kis­[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one]copper(II)
title_sort bis(nitrato-κo)tetra­kis­[1-phenyl-3-(1h-1,2,4-triazol-1-yl)propan-1-one]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201555/
https://www.ncbi.nlm.nih.gov/pubmed/22064784
http://dx.doi.org/10.1107/S160053681103529X
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