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(E)-Methyl 3-(4-chlorophenyl)-2-{2-[(E)-(hydroxyimino)methyl]phenoxymethyl}acrylate
In the title compound, C(18)H(16)ClNO(4), the dihedral angle between the mean planes through the aromatic rings is 83.8 (8)°. The hydroxyethanimine group is essentially coplanar with the ring to which it is attached [O—N—C—C torsion angle = −177.96 (13)°]. The molecules are linked into centrosymm...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201559/ https://www.ncbi.nlm.nih.gov/pubmed/22064839 http://dx.doi.org/10.1107/S1600536811038372 |
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author | SakthiMurugesan, K. Govindan, E. Srinivasan, J. Bakthadoss, M. SubbiahPandi, A. |
author_facet | SakthiMurugesan, K. Govindan, E. Srinivasan, J. Bakthadoss, M. SubbiahPandi, A. |
author_sort | SakthiMurugesan, K. |
collection | PubMed |
description | In the title compound, C(18)H(16)ClNO(4), the dihedral angle between the mean planes through the aromatic rings is 83.8 (8)°. The hydroxyethanimine group is essentially coplanar with the ring to which it is attached [O—N—C—C torsion angle = −177.96 (13)°]. The molecules are linked into centrosymmetric R (2) (2)(6) dimers via O—H⋯N hydrogen bonds. The crystal packing is further stabilized by C—H⋯O interactions. |
format | Online Article Text |
id | pubmed-3201559 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32015592011-11-06 (E)-Methyl 3-(4-chlorophenyl)-2-{2-[(E)-(hydroxyimino)methyl]phenoxymethyl}acrylate SakthiMurugesan, K. Govindan, E. Srinivasan, J. Bakthadoss, M. SubbiahPandi, A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(16)ClNO(4), the dihedral angle between the mean planes through the aromatic rings is 83.8 (8)°. The hydroxyethanimine group is essentially coplanar with the ring to which it is attached [O—N—C—C torsion angle = −177.96 (13)°]. The molecules are linked into centrosymmetric R (2) (2)(6) dimers via O—H⋯N hydrogen bonds. The crystal packing is further stabilized by C—H⋯O interactions. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201559/ /pubmed/22064839 http://dx.doi.org/10.1107/S1600536811038372 Text en © SakthiMurugesan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers SakthiMurugesan, K. Govindan, E. Srinivasan, J. Bakthadoss, M. SubbiahPandi, A. (E)-Methyl 3-(4-chlorophenyl)-2-{2-[(E)-(hydroxyimino)methyl]phenoxymethyl}acrylate |
title | (E)-Methyl 3-(4-chlorophenyl)-2-{2-[(E)-(hydroxyimino)methyl]phenoxymethyl}acrylate |
title_full | (E)-Methyl 3-(4-chlorophenyl)-2-{2-[(E)-(hydroxyimino)methyl]phenoxymethyl}acrylate |
title_fullStr | (E)-Methyl 3-(4-chlorophenyl)-2-{2-[(E)-(hydroxyimino)methyl]phenoxymethyl}acrylate |
title_full_unstemmed | (E)-Methyl 3-(4-chlorophenyl)-2-{2-[(E)-(hydroxyimino)methyl]phenoxymethyl}acrylate |
title_short | (E)-Methyl 3-(4-chlorophenyl)-2-{2-[(E)-(hydroxyimino)methyl]phenoxymethyl}acrylate |
title_sort | (e)-methyl 3-(4-chlorophenyl)-2-{2-[(e)-(hydroxyimino)methyl]phenoxymethyl}acrylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201559/ https://www.ncbi.nlm.nih.gov/pubmed/22064839 http://dx.doi.org/10.1107/S1600536811038372 |
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