catena-Poly[[dichloridomercury(II)]-μ-1,4-bis­[(pyridin-2-yl)meth­oxy]benzene-κ(2) N:N′]

In the title compound, [HgCl(2)(C(18)H(16)N(2)O(2))](n), the Hg(II) atom is four-coordinated in a distorted tetra­hedral environment defined by two Cl atoms and two N atoms from two 1,4-bis­(pyridin-2-ylmeth­oxy)benzene ligands. The ligand shows a non-coplanar conformation, in which the dihedral ang...

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Detalles Bibliográficos
Autores principales: Liu, Ying, Zhang, Hong-Sen, Hu, Ming-Xing, Hou, Guang-Feng, Gao, Jin-Sheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201560/
https://www.ncbi.nlm.nih.gov/pubmed/22064900
http://dx.doi.org/10.1107/S1600536811038323
Descripción
Sumario:In the title compound, [HgCl(2)(C(18)H(16)N(2)O(2))](n), the Hg(II) atom is four-coordinated in a distorted tetra­hedral environment defined by two Cl atoms and two N atoms from two 1,4-bis­(pyridin-2-ylmeth­oxy)benzene ligands. The ligand shows a non-coplanar conformation, in which the dihedral angles between the two terminal pyridine rings and the linking benzene ring are 7.275 (17) and 74.020 (14)°. The flexible ligands link the Hg(II) atoms into a chain running along [010], with an Hg⋯Hg separation of 10.335 (5) Å, which is equal to the b axis. The chains are connected by C—H⋯O and C—H⋯Cl hydrogen bonds.

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