catena-Poly[[dichloridomercury(II)]-μ-1,4-bis­[(pyridin-2-yl)meth­oxy]benzene-κ(2) N:N′]

In the title compound, [HgCl(2)(C(18)H(16)N(2)O(2))](n), the Hg(II) atom is four-coordinated in a distorted tetra­hedral environment defined by two Cl atoms and two N atoms from two 1,4-bis­(pyridin-2-ylmeth­oxy)benzene ligands. The ligand shows a non-coplanar conformation, in which the dihedral ang...

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Autores principales: Liu, Ying, Zhang, Hong-Sen, Hu, Ming-Xing, Hou, Guang-Feng, Gao, Jin-Sheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201560/
https://www.ncbi.nlm.nih.gov/pubmed/22064900
http://dx.doi.org/10.1107/S1600536811038323
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author Liu, Ying
Zhang, Hong-Sen
Hu, Ming-Xing
Hou, Guang-Feng
Gao, Jin-Sheng
author_facet Liu, Ying
Zhang, Hong-Sen
Hu, Ming-Xing
Hou, Guang-Feng
Gao, Jin-Sheng
author_sort Liu, Ying
collection PubMed
description In the title compound, [HgCl(2)(C(18)H(16)N(2)O(2))](n), the Hg(II) atom is four-coordinated in a distorted tetra­hedral environment defined by two Cl atoms and two N atoms from two 1,4-bis­(pyridin-2-ylmeth­oxy)benzene ligands. The ligand shows a non-coplanar conformation, in which the dihedral angles between the two terminal pyridine rings and the linking benzene ring are 7.275 (17) and 74.020 (14)°. The flexible ligands link the Hg(II) atoms into a chain running along [010], with an Hg⋯Hg separation of 10.335 (5) Å, which is equal to the b axis. The chains are connected by C—H⋯O and C—H⋯Cl hydrogen bonds.
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spelling pubmed-32015602011-11-06 catena-Poly[[dichloridomercury(II)]-μ-1,4-bis­[(pyridin-2-yl)meth­oxy]benzene-κ(2) N:N′] Liu, Ying Zhang, Hong-Sen Hu, Ming-Xing Hou, Guang-Feng Gao, Jin-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [HgCl(2)(C(18)H(16)N(2)O(2))](n), the Hg(II) atom is four-coordinated in a distorted tetra­hedral environment defined by two Cl atoms and two N atoms from two 1,4-bis­(pyridin-2-ylmeth­oxy)benzene ligands. The ligand shows a non-coplanar conformation, in which the dihedral angles between the two terminal pyridine rings and the linking benzene ring are 7.275 (17) and 74.020 (14)°. The flexible ligands link the Hg(II) atoms into a chain running along [010], with an Hg⋯Hg separation of 10.335 (5) Å, which is equal to the b axis. The chains are connected by C—H⋯O and C—H⋯Cl hydrogen bonds. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201560/ /pubmed/22064900 http://dx.doi.org/10.1107/S1600536811038323 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Ying
Zhang, Hong-Sen
Hu, Ming-Xing
Hou, Guang-Feng
Gao, Jin-Sheng
catena-Poly[[dichloridomercury(II)]-μ-1,4-bis­[(pyridin-2-yl)meth­oxy]benzene-κ(2) N:N′]
title catena-Poly[[dichloridomercury(II)]-μ-1,4-bis­[(pyridin-2-yl)meth­oxy]benzene-κ(2) N:N′]
title_full catena-Poly[[dichloridomercury(II)]-μ-1,4-bis­[(pyridin-2-yl)meth­oxy]benzene-κ(2) N:N′]
title_fullStr catena-Poly[[dichloridomercury(II)]-μ-1,4-bis­[(pyridin-2-yl)meth­oxy]benzene-κ(2) N:N′]
title_full_unstemmed catena-Poly[[dichloridomercury(II)]-μ-1,4-bis­[(pyridin-2-yl)meth­oxy]benzene-κ(2) N:N′]
title_short catena-Poly[[dichloridomercury(II)]-μ-1,4-bis­[(pyridin-2-yl)meth­oxy]benzene-κ(2) N:N′]
title_sort catena-poly[[dichloridomercury(ii)]-μ-1,4-bis­[(pyridin-2-yl)meth­oxy]benzene-κ(2) n:n′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201560/
https://www.ncbi.nlm.nih.gov/pubmed/22064900
http://dx.doi.org/10.1107/S1600536811038323
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