catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)samarium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]

The Sm atom in the cation of the title salt, {[Sm(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgS(4)W]}(n), is coordinated by eight O atoms derived from two chelating nitrate anions, and four hexamethylphos­phoramide ligand, defining a distorted square-antiprismatic geometry. The anions self-assemble into polyme...

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Detalles Bibliográficos
Autor principal: Zhang, Jinfang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201561/
https://www.ncbi.nlm.nih.gov/pubmed/22064929
http://dx.doi.org/10.1107/S1600536811035574
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author Zhang, Jinfang
author_facet Zhang, Jinfang
author_sort Zhang, Jinfang
collection PubMed
description The Sm atom in the cation of the title salt, {[Sm(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgS(4)W]}(n), is coordinated by eight O atoms derived from two chelating nitrate anions, and four hexamethylphos­phoramide ligand, defining a distorted square-antiprismatic geometry. The anions self-assemble into polymeric chains via W—S—Ag bridges having a [AgS(4)W] repeat unit; the W—Ag—W and Ag—W—Ag angles are 161.657 (17) and 153.978 (9)°, respectively. The title complex is isostructural with the Y, Yb, Eu, Nd, La and Dy isomorphs.
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spelling pubmed-32015612011-11-06 catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)samarium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]] Zhang, Jinfang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sm atom in the cation of the title salt, {[Sm(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgS(4)W]}(n), is coordinated by eight O atoms derived from two chelating nitrate anions, and four hexamethylphos­phoramide ligand, defining a distorted square-antiprismatic geometry. The anions self-assemble into polymeric chains via W—S—Ag bridges having a [AgS(4)W] repeat unit; the W—Ag—W and Ag—W—Ag angles are 161.657 (17) and 153.978 (9)°, respectively. The title complex is isostructural with the Y, Yb, Eu, Nd, La and Dy isomorphs. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201561/ /pubmed/22064929 http://dx.doi.org/10.1107/S1600536811035574 Text en © Jinfang Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Jinfang
catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)samarium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
title catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)samarium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
title_full catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)samarium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
title_fullStr catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)samarium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
title_full_unstemmed catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)samarium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
title_short catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)samarium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
title_sort catena-poly[[tetra­kis­(hexa­methyl­phospho­ramide-κo)bis­(nitrato-κ(2) o,o′)samarium(iii)] [silver(i)-di-μ-sulfido-tungstate(vi)-di-μ-sulfido]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201561/
https://www.ncbi.nlm.nih.gov/pubmed/22064929
http://dx.doi.org/10.1107/S1600536811035574
work_keys_str_mv AT zhangjinfang catenapolytetrakishexamethylphosphoramidekobisnitratok2oosamariumiiisilveridimsulfidotungstatevidimsulfido

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