Mössbauer Spectroscopy and X-ray Diffraction Study of (57)Fe-Labeled Tetrachloroferrate(III)-Based Magnetic Ionic Liquids

Four (57)Fe-labeled tetrachloroferrates(III) of organic cations (1-butyl-3-methylimidazolium, 1-allyl-3-methylimidazolium, 1-methyl-1-propylpyrrolidinium, tetraphenylphosphonium) were examined by temperature-dependent Mössbauer spectroscopy. The hyperfine and dynamic parameters of the iron(III) site...

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Autores principales: Herber, Rolfe H., Nowik, Israel, Kostner, Mirco E., Kahlenberg, Volker, Kreutz, Christoph, Laus, Gerhard, Schottenberger, Herwig
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International (MDPI) 2011
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3210985/
https://www.ncbi.nlm.nih.gov/pubmed/22072894
http://dx.doi.org/10.3390/ijms12106397
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author Herber, Rolfe H.
Nowik, Israel
Kostner, Mirco E.
Kahlenberg, Volker
Kreutz, Christoph
Laus, Gerhard
Schottenberger, Herwig
author_facet Herber, Rolfe H.
Nowik, Israel
Kostner, Mirco E.
Kahlenberg, Volker
Kreutz, Christoph
Laus, Gerhard
Schottenberger, Herwig
author_sort Herber, Rolfe H.
collection PubMed
description Four (57)Fe-labeled tetrachloroferrates(III) of organic cations (1-butyl-3-methylimidazolium, 1-allyl-3-methylimidazolium, 1-methyl-1-propylpyrrolidinium, tetraphenylphosphonium) were examined by temperature-dependent Mössbauer spectroscopy. The hyperfine and dynamic parameters of the iron(III) site were determined. Single crystal X-ray diffraction data of [Ph(4)P][FeCl(4)] were collected at four temperatures (295, 223, 173, and 123 K), and the dynamics of the iron atom inferred from the Mössbauer data and the single crystal U(i,j) parameters have been compared.
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spelling pubmed-32109852011-11-09 Mössbauer Spectroscopy and X-ray Diffraction Study of (57)Fe-Labeled Tetrachloroferrate(III)-Based Magnetic Ionic Liquids Herber, Rolfe H. Nowik, Israel Kostner, Mirco E. Kahlenberg, Volker Kreutz, Christoph Laus, Gerhard Schottenberger, Herwig Int J Mol Sci Article Four (57)Fe-labeled tetrachloroferrates(III) of organic cations (1-butyl-3-methylimidazolium, 1-allyl-3-methylimidazolium, 1-methyl-1-propylpyrrolidinium, tetraphenylphosphonium) were examined by temperature-dependent Mössbauer spectroscopy. The hyperfine and dynamic parameters of the iron(III) site were determined. Single crystal X-ray diffraction data of [Ph(4)P][FeCl(4)] were collected at four temperatures (295, 223, 173, and 123 K), and the dynamics of the iron atom inferred from the Mössbauer data and the single crystal U(i,j) parameters have been compared. Molecular Diversity Preservation International (MDPI) 2011-09-26 /pmc/articles/PMC3210985/ /pubmed/22072894 http://dx.doi.org/10.3390/ijms12106397 Text en © 2011 by the authors; licensee MDPI, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0 This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Herber, Rolfe H.
Nowik, Israel
Kostner, Mirco E.
Kahlenberg, Volker
Kreutz, Christoph
Laus, Gerhard
Schottenberger, Herwig
Mössbauer Spectroscopy and X-ray Diffraction Study of (57)Fe-Labeled Tetrachloroferrate(III)-Based Magnetic Ionic Liquids
title Mössbauer Spectroscopy and X-ray Diffraction Study of (57)Fe-Labeled Tetrachloroferrate(III)-Based Magnetic Ionic Liquids
title_full Mössbauer Spectroscopy and X-ray Diffraction Study of (57)Fe-Labeled Tetrachloroferrate(III)-Based Magnetic Ionic Liquids
title_fullStr Mössbauer Spectroscopy and X-ray Diffraction Study of (57)Fe-Labeled Tetrachloroferrate(III)-Based Magnetic Ionic Liquids
title_full_unstemmed Mössbauer Spectroscopy and X-ray Diffraction Study of (57)Fe-Labeled Tetrachloroferrate(III)-Based Magnetic Ionic Liquids
title_short Mössbauer Spectroscopy and X-ray Diffraction Study of (57)Fe-Labeled Tetrachloroferrate(III)-Based Magnetic Ionic Liquids
title_sort mössbauer spectroscopy and x-ray diffraction study of (57)fe-labeled tetrachloroferrate(iii)-based magnetic ionic liquids
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3210985/
https://www.ncbi.nlm.nih.gov/pubmed/22072894
http://dx.doi.org/10.3390/ijms12106397
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