Ion beam-induced shaping of Ni nanoparticles embedded in a silica matrix: from spherical to prolate shape

Present work reports the elongation of spherical Ni nanoparticles (NPs) parallel to each other, due to bombardment with 120 MeV Au(+9 )ions at a fluence of 5 × 10(13 )ions/cm(2). The Ni NPs embedded in silica matrix have been prepared by atom beam sputtering technique and subsequent annealing. The elongation of Ni NPs due to interaction with Au(+9 )ions as investigated by cross-sectional transmission electron microscopy (TEM) shows a strong dependence on initial Ni particle size and is explained on the basis of thermal spike model. Irradiation induces a change from single crystalline nature of spherical particles to polycrystalline nature of elongated particles. Magnetization measurements indicate that changes in coercivity (H(c)) and remanence ratio (M(r)/M(s)) are stronger in the ion beam direction due to the preferential easy axis of elongated particles in the beam direction.