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Polymer-stabilized palladium nanoparticles for catalytic membranes: ad hoc polymer fabrication

Metal nanoparticles are known as highly effective catalysts although their immobilization on solid supports is frequently required to prevent aggregation and to facilitate the catalyst application, recovery, and reuse. This paper reports the intermatrix synthesis of Pd(0 )nanoparticles in sulfonated...

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Detalles Bibliográficos
Autores principales: Domènech, Berta, Muñoz, Maria, Muraviev, Dmitri N, Macanás, Jorge
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3211501/
https://www.ncbi.nlm.nih.gov/pubmed/21711920
http://dx.doi.org/10.1186/1556-276X-6-406
Descripción
Sumario:Metal nanoparticles are known as highly effective catalysts although their immobilization on solid supports is frequently required to prevent aggregation and to facilitate the catalyst application, recovery, and reuse. This paper reports the intermatrix synthesis of Pd(0 )nanoparticles in sulfonated polyethersulfone with Cardo group membranes and their use as nanocomposite catalytic membrane reactors. The synthesized polymer and the corresponding nanocomposite were characterized by spectroscopic and microscopic techniques. The catalytic efficiency of catalytic membranes was evaluated by following the reduction of p-nitrophenol in the presence of NaBH(4).