Self-assembly of copper and cobalt complexes with hierarchical size and catalytic properties for hydroxylation of phenol

A feasible and effective self-assembly method to synthesize different scale coordination polymers in highly dilute solution (from nanocrystals to microcrystals and to bulk crystals) without any blocking agent has been described. The growth of crystalline particles was controlled by removing the part...

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Autores principales: Dong, Huaze, Tao, Wenbo, Bi, Jianhong, Milway, Victoria, Xu, Zhiqiang, Zhang, Shengyi, Meng, Xiangchun, Bi, Wentao, Li, Jian, Li, Meng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer 2011
Materias:
Nano Express
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3211998/
https://www.ncbi.nlm.nih.gov/pubmed/21824407
http://dx.doi.org/10.1186/1556-276X-6-484
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author Dong, Huaze
Tao, Wenbo
Bi, Jianhong
Milway, Victoria
Xu, Zhiqiang
Zhang, Shengyi
Meng, Xiangchun
Bi, Wentao
Li, Jian
Li, Meng
author_facet Dong, Huaze
Tao, Wenbo
Bi, Jianhong
Milway, Victoria
Xu, Zhiqiang
Zhang, Shengyi
Meng, Xiangchun
Bi, Wentao
Li, Jian
Li, Meng
author_sort Dong, Huaze
collection PubMed
description A feasible and effective self-assembly method to synthesize different scale coordination polymers in highly dilute solution (from nanocrystals to microcrystals and to bulk crystals) without any blocking agent has been described. The growth of crystalline particles was controlled by removing the particles at different reaction times to interrupt the growth at the desired size. The nano and microscale particles show better catalytic conversions and selectivities in the hydroxylation of phenols than the bulk crystals.
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spelling pubmed-32119982011-11-09 Self-assembly of copper and cobalt complexes with hierarchical size and catalytic properties for hydroxylation of phenol Dong, Huaze Tao, Wenbo Bi, Jianhong Milway, Victoria Xu, Zhiqiang Zhang, Shengyi Meng, Xiangchun Bi, Wentao Li, Jian Li, Meng Nanoscale Res Lett Nano Express A feasible and effective self-assembly method to synthesize different scale coordination polymers in highly dilute solution (from nanocrystals to microcrystals and to bulk crystals) without any blocking agent has been described. The growth of crystalline particles was controlled by removing the particles at different reaction times to interrupt the growth at the desired size. The nano and microscale particles show better catalytic conversions and selectivities in the hydroxylation of phenols than the bulk crystals. Springer 2011-08-08 /pmc/articles/PMC3211998/ /pubmed/21824407 http://dx.doi.org/10.1186/1556-276X-6-484 Text en Copyright ©2011 Dong et al; licensee Springer. http://creativecommons.org/licenses/by/2.0 This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Nano Express
Dong, Huaze
Tao, Wenbo
Bi, Jianhong
Milway, Victoria
Xu, Zhiqiang
Zhang, Shengyi
Meng, Xiangchun
Bi, Wentao
Li, Jian
Li, Meng
Self-assembly of copper and cobalt complexes with hierarchical size and catalytic properties for hydroxylation of phenol
title Self-assembly of copper and cobalt complexes with hierarchical size and catalytic properties for hydroxylation of phenol
title_full Self-assembly of copper and cobalt complexes with hierarchical size and catalytic properties for hydroxylation of phenol
title_fullStr Self-assembly of copper and cobalt complexes with hierarchical size and catalytic properties for hydroxylation of phenol
title_full_unstemmed Self-assembly of copper and cobalt complexes with hierarchical size and catalytic properties for hydroxylation of phenol
title_short Self-assembly of copper and cobalt complexes with hierarchical size and catalytic properties for hydroxylation of phenol
title_sort self-assembly of copper and cobalt complexes with hierarchical size and catalytic properties for hydroxylation of phenol
topic Nano Express
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3211998/
https://www.ncbi.nlm.nih.gov/pubmed/21824407
http://dx.doi.org/10.1186/1556-276X-6-484
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