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Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ(2) N,O (1)}nickel(II)
In the title compound, [Ni(C(15)H(13)FNO(2))(2)], the Ni(II) atom is tetracoordinated by two N atoms and two O atoms from two 2-[(4-fluorobenzyl)iminomethyl]-6-methoxyphenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the Ni(II) atom are trans to each other,...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212107/ https://www.ncbi.nlm.nih.gov/pubmed/22090809 http://dx.doi.org/10.1107/S1600536811025189 |
Sumario: | In the title compound, [Ni(C(15)H(13)FNO(2))(2)], the Ni(II) atom is tetracoordinated by two N atoms and two O atoms from two 2-[(4-fluorobenzyl)iminomethyl]-6-methoxyphenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the Ni(II) atom are trans to each other, as the Ni(II) atom lies on an inversion centre. In the fluorophenyl group, five C atoms and an F atom are disordered over two sets of positions of equal occupancy. In the crystal, the complex molecules are linked via intermolecular C—H⋯F hydrogen bonds, forming chains along [001]. |
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