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Bis{2-[(E)-(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolato-κ(2) N,O (1)}nickel(II)

In the title compound, [Ni(C(15)H(13)FNO(2))(2)], the Ni(II) atom is tetra­coordinated by two N atoms and two O atoms from two 2-[(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the Ni(II) atom are trans to each other,...

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Autores principales: Bahron, Hadariah, Tajuddin, Amalina Mohd, Ibrahim, Wan Nazihah Wan, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212107/
https://www.ncbi.nlm.nih.gov/pubmed/22090809
http://dx.doi.org/10.1107/S1600536811025189
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author Bahron, Hadariah
Tajuddin, Amalina Mohd
Ibrahim, Wan Nazihah Wan
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Bahron, Hadariah
Tajuddin, Amalina Mohd
Ibrahim, Wan Nazihah Wan
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Bahron, Hadariah
collection PubMed
description In the title compound, [Ni(C(15)H(13)FNO(2))(2)], the Ni(II) atom is tetra­coordinated by two N atoms and two O atoms from two 2-[(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the Ni(II) atom are trans to each other, as the Ni(II) atom lies on an inversion centre. In the fluoro­phenyl group, five C atoms and an F atom are disordered over two sets of positions of equal occupancy. In the crystal, the complex mol­ecules are linked via inter­molecular C—H⋯F hydrogen bonds, forming chains along [001].
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spelling pubmed-32121072011-11-16 Bis{2-[(E)-(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolato-κ(2) N,O (1)}nickel(II) Bahron, Hadariah Tajuddin, Amalina Mohd Ibrahim, Wan Nazihah Wan Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(15)H(13)FNO(2))(2)], the Ni(II) atom is tetra­coordinated by two N atoms and two O atoms from two 2-[(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the Ni(II) atom are trans to each other, as the Ni(II) atom lies on an inversion centre. In the fluoro­phenyl group, five C atoms and an F atom are disordered over two sets of positions of equal occupancy. In the crystal, the complex mol­ecules are linked via inter­molecular C—H⋯F hydrogen bonds, forming chains along [001]. International Union of Crystallography 2011-07-02 /pmc/articles/PMC3212107/ /pubmed/22090809 http://dx.doi.org/10.1107/S1600536811025189 Text en © Bahron et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bahron, Hadariah
Tajuddin, Amalina Mohd
Ibrahim, Wan Nazihah Wan
Hemamalini, Madhukar
Fun, Hoong-Kun
Bis{2-[(E)-(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolato-κ(2) N,O (1)}nickel(II)
title Bis{2-[(E)-(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolato-κ(2) N,O (1)}nickel(II)
title_full Bis{2-[(E)-(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolato-κ(2) N,O (1)}nickel(II)
title_fullStr Bis{2-[(E)-(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolato-κ(2) N,O (1)}nickel(II)
title_full_unstemmed Bis{2-[(E)-(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolato-κ(2) N,O (1)}nickel(II)
title_short Bis{2-[(E)-(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolato-κ(2) N,O (1)}nickel(II)
title_sort bis{2-[(e)-(4-fluoro­benz­yl)imino­meth­yl]-6-meth­oxy­phenolato-κ(2) n,o (1)}nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212107/
https://www.ncbi.nlm.nih.gov/pubmed/22090809
http://dx.doi.org/10.1107/S1600536811025189
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