Cargando…
Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ(2) N,O (1)}nickel(II)
In the title compound, [Ni(C(15)H(13)FNO(2))(2)], the Ni(II) atom is tetracoordinated by two N atoms and two O atoms from two 2-[(4-fluorobenzyl)iminomethyl]-6-methoxyphenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the Ni(II) atom are trans to each other,...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212107/ https://www.ncbi.nlm.nih.gov/pubmed/22090809 http://dx.doi.org/10.1107/S1600536811025189 |
_version_ | 1782215920006987776 |
---|---|
author | Bahron, Hadariah Tajuddin, Amalina Mohd Ibrahim, Wan Nazihah Wan Hemamalini, Madhukar Fun, Hoong-Kun |
author_facet | Bahron, Hadariah Tajuddin, Amalina Mohd Ibrahim, Wan Nazihah Wan Hemamalini, Madhukar Fun, Hoong-Kun |
author_sort | Bahron, Hadariah |
collection | PubMed |
description | In the title compound, [Ni(C(15)H(13)FNO(2))(2)], the Ni(II) atom is tetracoordinated by two N atoms and two O atoms from two 2-[(4-fluorobenzyl)iminomethyl]-6-methoxyphenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the Ni(II) atom are trans to each other, as the Ni(II) atom lies on an inversion centre. In the fluorophenyl group, five C atoms and an F atom are disordered over two sets of positions of equal occupancy. In the crystal, the complex molecules are linked via intermolecular C—H⋯F hydrogen bonds, forming chains along [001]. |
format | Online Article Text |
id | pubmed-3212107 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32121072011-11-16 Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ(2) N,O (1)}nickel(II) Bahron, Hadariah Tajuddin, Amalina Mohd Ibrahim, Wan Nazihah Wan Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(15)H(13)FNO(2))(2)], the Ni(II) atom is tetracoordinated by two N atoms and two O atoms from two 2-[(4-fluorobenzyl)iminomethyl]-6-methoxyphenolate ligands in a square-planar geometry. The two N atoms and two O atoms around the Ni(II) atom are trans to each other, as the Ni(II) atom lies on an inversion centre. In the fluorophenyl group, five C atoms and an F atom are disordered over two sets of positions of equal occupancy. In the crystal, the complex molecules are linked via intermolecular C—H⋯F hydrogen bonds, forming chains along [001]. International Union of Crystallography 2011-07-02 /pmc/articles/PMC3212107/ /pubmed/22090809 http://dx.doi.org/10.1107/S1600536811025189 Text en © Bahron et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bahron, Hadariah Tajuddin, Amalina Mohd Ibrahim, Wan Nazihah Wan Hemamalini, Madhukar Fun, Hoong-Kun Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ(2) N,O (1)}nickel(II) |
title | Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ(2)
N,O
(1)}nickel(II) |
title_full | Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ(2)
N,O
(1)}nickel(II) |
title_fullStr | Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ(2)
N,O
(1)}nickel(II) |
title_full_unstemmed | Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ(2)
N,O
(1)}nickel(II) |
title_short | Bis{2-[(E)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ(2)
N,O
(1)}nickel(II) |
title_sort | bis{2-[(e)-(4-fluorobenzyl)iminomethyl]-6-methoxyphenolato-κ(2)
n,o
(1)}nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212107/ https://www.ncbi.nlm.nih.gov/pubmed/22090809 http://dx.doi.org/10.1107/S1600536811025189 |
work_keys_str_mv | AT bahronhadariah bis2e4fluorobenzyliminomethyl6methoxyphenolatok2no1nickelii AT tajuddinamalinamohd bis2e4fluorobenzyliminomethyl6methoxyphenolatok2no1nickelii AT ibrahimwannazihahwan bis2e4fluorobenzyliminomethyl6methoxyphenolatok2no1nickelii AT hemamalinimadhukar bis2e4fluorobenzyliminomethyl6methoxyphenolatok2no1nickelii AT funhoongkun bis2e4fluorobenzyliminomethyl6methoxyphenolatok2no1nickelii |