1,1′,2,2′,3,3′,4,4′-Octa­methyl­ferro­cenium 2,5-dibromo-4-hy­droxy-3,6-dioxocyclo­hexa-1,4-dien-1-olate

In the title salt, octa­methyl­ferrocenium bromanilate, [Fe(C(9)H(13))(2)](C(6)HBr(2)O(4)), the Fe atom and the bromanilate anion lie on a mirror plane. The octa­methyl­ferrocenium cation adopts an eclipsed conformation. An intra­molecular O—H⋯O hydrogen bond is present in the bromanilate anion. In...

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Detalles Bibliográficos
Autor principal: Mochida, Tomoyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212108/
https://www.ncbi.nlm.nih.gov/pubmed/22090810
http://dx.doi.org/10.1107/S1600536811025499
Descripción
Sumario:In the title salt, octa­methyl­ferrocenium bromanilate, [Fe(C(9)H(13))(2)](C(6)HBr(2)O(4)), the Fe atom and the bromanilate anion lie on a mirror plane. The octa­methyl­ferrocenium cation adopts an eclipsed conformation. An intra­molecular O—H⋯O hydrogen bond is present in the bromanilate anion. In the crystal, the cations and anions are stacked alternately, forming a one-dimensional columnar structure along [010].

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