1,1′,2,2′,3,3′,4,4′-Octa­methyl­ferro­cenium 2,5-dibromo-4-hy­droxy-3,6-dioxocyclo­hexa-1,4-dien-1-olate

In the title salt, octa­methyl­ferrocenium bromanilate, [Fe(C(9)H(13))(2)](C(6)HBr(2)O(4)), the Fe atom and the bromanilate anion lie on a mirror plane. The octa­methyl­ferrocenium cation adopts an eclipsed conformation. An intra­molecular O—H⋯O hydrogen bond is present in the bromanilate anion. In...

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Detalles Bibliográficos
Autor principal: Mochida, Tomoyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212108/
https://www.ncbi.nlm.nih.gov/pubmed/22090810
http://dx.doi.org/10.1107/S1600536811025499
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author Mochida, Tomoyuki
author_facet Mochida, Tomoyuki
author_sort Mochida, Tomoyuki
collection PubMed
description In the title salt, octa­methyl­ferrocenium bromanilate, [Fe(C(9)H(13))(2)](C(6)HBr(2)O(4)), the Fe atom and the bromanilate anion lie on a mirror plane. The octa­methyl­ferrocenium cation adopts an eclipsed conformation. An intra­molecular O—H⋯O hydrogen bond is present in the bromanilate anion. In the crystal, the cations and anions are stacked alternately, forming a one-dimensional columnar structure along [010].
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spelling pubmed-32121082011-11-16 1,1′,2,2′,3,3′,4,4′-Octa­methyl­ferro­cenium 2,5-dibromo-4-hy­droxy-3,6-dioxocyclo­hexa-1,4-dien-1-olate Mochida, Tomoyuki Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, octa­methyl­ferrocenium bromanilate, [Fe(C(9)H(13))(2)](C(6)HBr(2)O(4)), the Fe atom and the bromanilate anion lie on a mirror plane. The octa­methyl­ferrocenium cation adopts an eclipsed conformation. An intra­molecular O—H⋯O hydrogen bond is present in the bromanilate anion. In the crystal, the cations and anions are stacked alternately, forming a one-dimensional columnar structure along [010]. International Union of Crystallography 2011-07-02 /pmc/articles/PMC3212108/ /pubmed/22090810 http://dx.doi.org/10.1107/S1600536811025499 Text en © Tomoyuki Mochida 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mochida, Tomoyuki
1,1′,2,2′,3,3′,4,4′-Octa­methyl­ferro­cenium 2,5-dibromo-4-hy­droxy-3,6-dioxocyclo­hexa-1,4-dien-1-olate
title 1,1′,2,2′,3,3′,4,4′-Octa­methyl­ferro­cenium 2,5-dibromo-4-hy­droxy-3,6-dioxocyclo­hexa-1,4-dien-1-olate
title_full 1,1′,2,2′,3,3′,4,4′-Octa­methyl­ferro­cenium 2,5-dibromo-4-hy­droxy-3,6-dioxocyclo­hexa-1,4-dien-1-olate
title_fullStr 1,1′,2,2′,3,3′,4,4′-Octa­methyl­ferro­cenium 2,5-dibromo-4-hy­droxy-3,6-dioxocyclo­hexa-1,4-dien-1-olate
title_full_unstemmed 1,1′,2,2′,3,3′,4,4′-Octa­methyl­ferro­cenium 2,5-dibromo-4-hy­droxy-3,6-dioxocyclo­hexa-1,4-dien-1-olate
title_short 1,1′,2,2′,3,3′,4,4′-Octa­methyl­ferro­cenium 2,5-dibromo-4-hy­droxy-3,6-dioxocyclo­hexa-1,4-dien-1-olate
title_sort 1,1′,2,2′,3,3′,4,4′-octa­methyl­ferro­cenium 2,5-dibromo-4-hy­droxy-3,6-dioxocyclo­hexa-1,4-dien-1-olate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212108/
https://www.ncbi.nlm.nih.gov/pubmed/22090810
http://dx.doi.org/10.1107/S1600536811025499
work_keys_str_mv AT mochidatomoyuki 11223344octamethylferrocenium25dibromo4hydroxy36dioxocyclohexa14dien1olate

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