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catena-Poly[[bis­(1H-imidazole-κN(3))copper(II)]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)]

In the title compound, [Cu(C(8)H(4)O(4))(C(3)H(4)N(2))(2)](n), the Cu(II) atom is four-coordinated by two carboxyl­ate O atoms from two different terephthalate ligands and two N atoms from two imidazole ligands in a slightly distorted square-planar coordination environment. Each terephthalate ligand...

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Autor principal: Xu, Qian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212110/
https://www.ncbi.nlm.nih.gov/pubmed/22090812
http://dx.doi.org/10.1107/S1600536811024822
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author Xu, Qian
author_facet Xu, Qian
author_sort Xu, Qian
collection PubMed
description In the title compound, [Cu(C(8)H(4)O(4))(C(3)H(4)N(2))(2)](n), the Cu(II) atom is four-coordinated by two carboxyl­ate O atoms from two different terephthalate ligands and two N atoms from two imidazole ligands in a slightly distorted square-planar coordination environment. Each terephthalate ligand acts as a bis-monodentate ligand that binds two Cu(II) atoms, thus forming two unique chains extending parallel to [110]. The imidazole ligands are attached on both sides of the chains.
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spelling pubmed-32121102011-11-16 catena-Poly[[bis­(1H-imidazole-κN(3))copper(II)]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)] Xu, Qian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(8)H(4)O(4))(C(3)H(4)N(2))(2)](n), the Cu(II) atom is four-coordinated by two carboxyl­ate O atoms from two different terephthalate ligands and two N atoms from two imidazole ligands in a slightly distorted square-planar coordination environment. Each terephthalate ligand acts as a bis-monodentate ligand that binds two Cu(II) atoms, thus forming two unique chains extending parallel to [110]. The imidazole ligands are attached on both sides of the chains. International Union of Crystallography 2011-07-02 /pmc/articles/PMC3212110/ /pubmed/22090812 http://dx.doi.org/10.1107/S1600536811024822 Text en © Qian Xu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Qian
catena-Poly[[bis­(1H-imidazole-κN(3))copper(II)]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)]
title catena-Poly[[bis­(1H-imidazole-κN(3))copper(II)]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)]
title_full catena-Poly[[bis­(1H-imidazole-κN(3))copper(II)]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)]
title_fullStr catena-Poly[[bis­(1H-imidazole-κN(3))copper(II)]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)]
title_full_unstemmed catena-Poly[[bis­(1H-imidazole-κN(3))copper(II)]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)]
title_short catena-Poly[[bis­(1H-imidazole-κN(3))copper(II)]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)]
title_sort catena-poly[[bis­(1h-imidazole-κn(3))copper(ii)]-μ-benzene-1,4-dicarboxyl­ato-κ(2) o (1):o (4)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212110/
https://www.ncbi.nlm.nih.gov/pubmed/22090812
http://dx.doi.org/10.1107/S1600536811024822
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