Potassium N-bromo-2-methyl­benzene­sulfonamidate sesquihydrate

In the structure of the title compound, K(+)·C(7)H(7)BrNO(2)S(−)·1.5H(2)O, the K(+) ion is hepta­coordinated by three O atoms from water mol­ecules and by four sulfonyl O atoms of N-bromo-2-methyl­benzene­sulfonamide anions. The S—N distance of 1.577 (5) Å is consistent with an S=N double bond. The...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Shakuntala, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212111/
https://www.ncbi.nlm.nih.gov/pubmed/22090813
http://dx.doi.org/10.1107/S1600536811025153
Descripción
Sumario:In the structure of the title compound, K(+)·C(7)H(7)BrNO(2)S(−)·1.5H(2)O, the K(+) ion is hepta­coordinated by three O atoms from water mol­ecules and by four sulfonyl O atoms of N-bromo-2-methyl­benzene­sulfonamide anions. The S—N distance of 1.577 (5) Å is consistent with an S=N double bond. The crystal structure comprises sheets in the ac plane which are further stabilized by O—H⋯Br and O—H⋯N hydrogen bonds.

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