Potassium N-bromo-2-methyl­benzene­sulfonamidate sesquihydrate

In the structure of the title compound, K(+)·C(7)H(7)BrNO(2)S(−)·1.5H(2)O, the K(+) ion is hepta­coordinated by three O atoms from water mol­ecules and by four sulfonyl O atoms of N-bromo-2-methyl­benzene­sulfonamide anions. The S—N distance of 1.577 (5) Å is consistent with an S=N double bond. The...

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Autores principales: Gowda, B. Thimme, Foro, Sabine, Shakuntala, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212111/
https://www.ncbi.nlm.nih.gov/pubmed/22090813
http://dx.doi.org/10.1107/S1600536811025153
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author Gowda, B. Thimme
Foro, Sabine
Shakuntala, K.
author_facet Gowda, B. Thimme
Foro, Sabine
Shakuntala, K.
author_sort Gowda, B. Thimme
collection PubMed
description In the structure of the title compound, K(+)·C(7)H(7)BrNO(2)S(−)·1.5H(2)O, the K(+) ion is hepta­coordinated by three O atoms from water mol­ecules and by four sulfonyl O atoms of N-bromo-2-methyl­benzene­sulfonamide anions. The S—N distance of 1.577 (5) Å is consistent with an S=N double bond. The crystal structure comprises sheets in the ac plane which are further stabilized by O—H⋯Br and O—H⋯N hydrogen bonds.
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spelling pubmed-32121112011-11-16 Potassium N-bromo-2-methyl­benzene­sulfonamidate sesquihydrate Gowda, B. Thimme Foro, Sabine Shakuntala, K. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, K(+)·C(7)H(7)BrNO(2)S(−)·1.5H(2)O, the K(+) ion is hepta­coordinated by three O atoms from water mol­ecules and by four sulfonyl O atoms of N-bromo-2-methyl­benzene­sulfonamide anions. The S—N distance of 1.577 (5) Å is consistent with an S=N double bond. The crystal structure comprises sheets in the ac plane which are further stabilized by O—H⋯Br and O—H⋯N hydrogen bonds. International Union of Crystallography 2011-07-02 /pmc/articles/PMC3212111/ /pubmed/22090813 http://dx.doi.org/10.1107/S1600536811025153 Text en © Gowda et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gowda, B. Thimme
Foro, Sabine
Shakuntala, K.
Potassium N-bromo-2-methyl­benzene­sulfonamidate sesquihydrate
title Potassium N-bromo-2-methyl­benzene­sulfonamidate sesquihydrate
title_full Potassium N-bromo-2-methyl­benzene­sulfonamidate sesquihydrate
title_fullStr Potassium N-bromo-2-methyl­benzene­sulfonamidate sesquihydrate
title_full_unstemmed Potassium N-bromo-2-methyl­benzene­sulfonamidate sesquihydrate
title_short Potassium N-bromo-2-methyl­benzene­sulfonamidate sesquihydrate
title_sort potassium n-bromo-2-methyl­benzene­sulfonamidate sesquihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212111/
https://www.ncbi.nlm.nih.gov/pubmed/22090813
http://dx.doi.org/10.1107/S1600536811025153
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