1,2-Dimethyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­chloridocuprate(II)

In the title compound, (C(8)H(18)N(2))[CuCl(4)], torsion angles on the ethyl­ene bridges of the 1,4-diazo­niabicyclo­[2.2.2]octane fragment are in the range 11.9 (5)–15.0 (5)° and the [CuCl(4)](2−) anion has a strongly distorted tetra­hedral geometry. The cation is connected to the anion via three-c...

Descripción completa

Detalles Bibliográficos
Autor principal: Rong, Tao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212112/
https://www.ncbi.nlm.nih.gov/pubmed/22090814
http://dx.doi.org/10.1107/S1600536811025347
_version_ 1782215921102749696
author Rong, Tao
author_facet Rong, Tao
author_sort Rong, Tao
collection PubMed
description In the title compound, (C(8)H(18)N(2))[CuCl(4)], torsion angles on the ethyl­ene bridges of the 1,4-diazo­niabicyclo­[2.2.2]octane fragment are in the range 11.9 (5)–15.0 (5)° and the [CuCl(4)](2−) anion has a strongly distorted tetra­hedral geometry. The cation is connected to the anion via three-center N—H⋯Cl hydrogen bonds.
format Online
Article
Text
id pubmed-3212112
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32121122011-11-16 1,2-Dimethyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­chloridocuprate(II) Rong, Tao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(8)H(18)N(2))[CuCl(4)], torsion angles on the ethyl­ene bridges of the 1,4-diazo­niabicyclo­[2.2.2]octane fragment are in the range 11.9 (5)–15.0 (5)° and the [CuCl(4)](2−) anion has a strongly distorted tetra­hedral geometry. The cation is connected to the anion via three-center N—H⋯Cl hydrogen bonds. International Union of Crystallography 2011-07-02 /pmc/articles/PMC3212112/ /pubmed/22090814 http://dx.doi.org/10.1107/S1600536811025347 Text en © Tao Rong 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rong, Tao
1,2-Dimethyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­chloridocuprate(II)
title 1,2-Dimethyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­chloridocuprate(II)
title_full 1,2-Dimethyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­chloridocuprate(II)
title_fullStr 1,2-Dimethyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­chloridocuprate(II)
title_full_unstemmed 1,2-Dimethyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­chloridocuprate(II)
title_short 1,2-Dimethyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­chloridocuprate(II)
title_sort 1,2-dimethyl-1,4-diazo­niabicyclo­[2.2.2]octane tetra­chloridocuprate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212112/
https://www.ncbi.nlm.nih.gov/pubmed/22090814
http://dx.doi.org/10.1107/S1600536811025347
work_keys_str_mv AT rongtao 12dimethyl14diazoniabicyclo222octanetetrachloridocuprateii

Ejemplares similares