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Dichlorido(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc acetonitrile monosolvate

The title complex, [FeZn(C(5)H(5))Cl(2)(C(20)H(14)N(3))]·CH(3)CN, is composed of one Zn(II) atom, one 4′-ferrocenyl-2,2′:6′,2′′-terpyridine (fctpy) ligand, two Cl atoms and one acetonitrile solvent mol­ecule. The Zn(II) atom is five-coordinated in a trigonal–bipyramidal geometry by the tridentate ch...

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Detalles Bibliográficos
Autores principales: Tang, Si-Ping, Feng, Yong-Lan, Kuang, Dai-Zhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212113/
https://www.ncbi.nlm.nih.gov/pubmed/22090815
http://dx.doi.org/10.1107/S1600536811024950
Descripción
Sumario:The title complex, [FeZn(C(5)H(5))Cl(2)(C(20)H(14)N(3))]·CH(3)CN, is composed of one Zn(II) atom, one 4′-ferrocenyl-2,2′:6′,2′′-terpyridine (fctpy) ligand, two Cl atoms and one acetonitrile solvent mol­ecule. The Zn(II) atom is five-coordinated in a trigonal–bipyramidal geometry by the tridentate chelating fctpy ligand and two Cl atoms.