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Octa­butylbis[μ(2)-4-(diethyl­amino)­benzoato-κ(2) O:O′]bis­[4-(diethyl­amino)­benzoato-κO]di-μ(3)-oxido-tetra­tin(IV)

The asymmetric unit of the title complex, [Sn(4)(C(4)H(9))(8)(C(11)H(14)NO(2))(4)O(2)], consists of two crystallographically independent half-mol­ecules. The other halves are generated by crystallographic inversion centers. In each tetra­nuclear mol­ecule, both of the two independent Sn atoms are fi...

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Detalles Bibliográficos
Autores principales: Win, Yip-Foo, Choong, Chen-Shang, Ha, Sie-Tiong, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212114/
https://www.ncbi.nlm.nih.gov/pubmed/22090816
http://dx.doi.org/10.1107/S1600536811025360
Descripción
Sumario:The asymmetric unit of the title complex, [Sn(4)(C(4)H(9))(8)(C(11)H(14)NO(2))(4)O(2)], consists of two crystallographically independent half-mol­ecules. The other halves are generated by crystallographic inversion centers. In each tetra­nuclear mol­ecule, both of the two independent Sn atoms are five-coordinated, with distorted trigonal–bipyramidal SnC(2)O(3) geometries. One Sn atom is coordinated by two butyl groups, one O atom of the benzoate anion and two bridging O atoms, whereas the other Sn atom is coordinated by two butyl groups, two O atoms of the benzoate anions and a bridging O atom. All the butyl groups are equatorial with respect to the SnO(3) trigonal plane. Weak intra­molecular C—H⋯O hydrogen bonds stabilize the mol­ecular structures. In one mol­ecule, two of the butyl groups and the bridging benzoate anion are each disordered over two positions.