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Octabutylbis[μ(2)-4-(diethylamino)benzoato-κ(2) O:O′]bis[4-(diethylamino)benzoato-κO]di-μ(3)-oxido-tetratin(IV)
The asymmetric unit of the title complex, [Sn(4)(C(4)H(9))(8)(C(11)H(14)NO(2))(4)O(2)], consists of two crystallographically independent half-molecules. The other halves are generated by crystallographic inversion centers. In each tetranuclear molecule, both of the two independent Sn atoms are fi...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212114/ https://www.ncbi.nlm.nih.gov/pubmed/22090816 http://dx.doi.org/10.1107/S1600536811025360 |
Sumario: | The asymmetric unit of the title complex, [Sn(4)(C(4)H(9))(8)(C(11)H(14)NO(2))(4)O(2)], consists of two crystallographically independent half-molecules. The other halves are generated by crystallographic inversion centers. In each tetranuclear molecule, both of the two independent Sn atoms are five-coordinated, with distorted trigonal–bipyramidal SnC(2)O(3) geometries. One Sn atom is coordinated by two butyl groups, one O atom of the benzoate anion and two bridging O atoms, whereas the other Sn atom is coordinated by two butyl groups, two O atoms of the benzoate anions and a bridging O atom. All the butyl groups are equatorial with respect to the SnO(3) trigonal plane. Weak intramolecular C—H⋯O hydrogen bonds stabilize the molecular structures. In one molecule, two of the butyl groups and the bridging benzoate anion are each disordered over two positions. |
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