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Octa­butylbis[μ(2)-4-(diethyl­amino)­benzoato-κ(2) O:O′]bis­[4-(diethyl­amino)­benzoato-κO]di-μ(3)-oxido-tetra­tin(IV)

The asymmetric unit of the title complex, [Sn(4)(C(4)H(9))(8)(C(11)H(14)NO(2))(4)O(2)], consists of two crystallographically independent half-mol­ecules. The other halves are generated by crystallographic inversion centers. In each tetra­nuclear mol­ecule, both of the two independent Sn atoms are fi...

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Autores principales: Win, Yip-Foo, Choong, Chen-Shang, Ha, Sie-Tiong, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212114/
https://www.ncbi.nlm.nih.gov/pubmed/22090816
http://dx.doi.org/10.1107/S1600536811025360
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author Win, Yip-Foo
Choong, Chen-Shang
Ha, Sie-Tiong
Yeap, Chin Sing
Fun, Hoong-Kun
author_facet Win, Yip-Foo
Choong, Chen-Shang
Ha, Sie-Tiong
Yeap, Chin Sing
Fun, Hoong-Kun
author_sort Win, Yip-Foo
collection PubMed
description The asymmetric unit of the title complex, [Sn(4)(C(4)H(9))(8)(C(11)H(14)NO(2))(4)O(2)], consists of two crystallographically independent half-mol­ecules. The other halves are generated by crystallographic inversion centers. In each tetra­nuclear mol­ecule, both of the two independent Sn atoms are five-coordinated, with distorted trigonal–bipyramidal SnC(2)O(3) geometries. One Sn atom is coordinated by two butyl groups, one O atom of the benzoate anion and two bridging O atoms, whereas the other Sn atom is coordinated by two butyl groups, two O atoms of the benzoate anions and a bridging O atom. All the butyl groups are equatorial with respect to the SnO(3) trigonal plane. Weak intra­molecular C—H⋯O hydrogen bonds stabilize the mol­ecular structures. In one mol­ecule, two of the butyl groups and the bridging benzoate anion are each disordered over two positions.
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spelling pubmed-32121142011-11-16 Octa­butylbis[μ(2)-4-(diethyl­amino)­benzoato-κ(2) O:O′]bis­[4-(diethyl­amino)­benzoato-κO]di-μ(3)-oxido-tetra­tin(IV) Win, Yip-Foo Choong, Chen-Shang Ha, Sie-Tiong Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Sn(4)(C(4)H(9))(8)(C(11)H(14)NO(2))(4)O(2)], consists of two crystallographically independent half-mol­ecules. The other halves are generated by crystallographic inversion centers. In each tetra­nuclear mol­ecule, both of the two independent Sn atoms are five-coordinated, with distorted trigonal–bipyramidal SnC(2)O(3) geometries. One Sn atom is coordinated by two butyl groups, one O atom of the benzoate anion and two bridging O atoms, whereas the other Sn atom is coordinated by two butyl groups, two O atoms of the benzoate anions and a bridging O atom. All the butyl groups are equatorial with respect to the SnO(3) trigonal plane. Weak intra­molecular C—H⋯O hydrogen bonds stabilize the mol­ecular structures. In one mol­ecule, two of the butyl groups and the bridging benzoate anion are each disordered over two positions. International Union of Crystallography 2011-07-02 /pmc/articles/PMC3212114/ /pubmed/22090816 http://dx.doi.org/10.1107/S1600536811025360 Text en © Win et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Win, Yip-Foo
Choong, Chen-Shang
Ha, Sie-Tiong
Yeap, Chin Sing
Fun, Hoong-Kun
Octa­butylbis[μ(2)-4-(diethyl­amino)­benzoato-κ(2) O:O′]bis­[4-(diethyl­amino)­benzoato-κO]di-μ(3)-oxido-tetra­tin(IV)
title Octa­butylbis[μ(2)-4-(diethyl­amino)­benzoato-κ(2) O:O′]bis­[4-(diethyl­amino)­benzoato-κO]di-μ(3)-oxido-tetra­tin(IV)
title_full Octa­butylbis[μ(2)-4-(diethyl­amino)­benzoato-κ(2) O:O′]bis­[4-(diethyl­amino)­benzoato-κO]di-μ(3)-oxido-tetra­tin(IV)
title_fullStr Octa­butylbis[μ(2)-4-(diethyl­amino)­benzoato-κ(2) O:O′]bis­[4-(diethyl­amino)­benzoato-κO]di-μ(3)-oxido-tetra­tin(IV)
title_full_unstemmed Octa­butylbis[μ(2)-4-(diethyl­amino)­benzoato-κ(2) O:O′]bis­[4-(diethyl­amino)­benzoato-κO]di-μ(3)-oxido-tetra­tin(IV)
title_short Octa­butylbis[μ(2)-4-(diethyl­amino)­benzoato-κ(2) O:O′]bis­[4-(diethyl­amino)­benzoato-κO]di-μ(3)-oxido-tetra­tin(IV)
title_sort octa­butylbis[μ(2)-4-(diethyl­amino)­benzoato-κ(2) o:o′]bis­[4-(diethyl­amino)­benzoato-κo]di-μ(3)-oxido-tetra­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212114/
https://www.ncbi.nlm.nih.gov/pubmed/22090816
http://dx.doi.org/10.1107/S1600536811025360
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