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Octabutylbis[μ(2)-4-(diethylamino)benzoato-κ(2) O:O′]bis[4-(diethylamino)benzoato-κO]di-μ(3)-oxido-tetratin(IV)
The asymmetric unit of the title complex, [Sn(4)(C(4)H(9))(8)(C(11)H(14)NO(2))(4)O(2)], consists of two crystallographically independent half-molecules. The other halves are generated by crystallographic inversion centers. In each tetranuclear molecule, both of the two independent Sn atoms are fi...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212114/ https://www.ncbi.nlm.nih.gov/pubmed/22090816 http://dx.doi.org/10.1107/S1600536811025360 |
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author | Win, Yip-Foo Choong, Chen-Shang Ha, Sie-Tiong Yeap, Chin Sing Fun, Hoong-Kun |
author_facet | Win, Yip-Foo Choong, Chen-Shang Ha, Sie-Tiong Yeap, Chin Sing Fun, Hoong-Kun |
author_sort | Win, Yip-Foo |
collection | PubMed |
description | The asymmetric unit of the title complex, [Sn(4)(C(4)H(9))(8)(C(11)H(14)NO(2))(4)O(2)], consists of two crystallographically independent half-molecules. The other halves are generated by crystallographic inversion centers. In each tetranuclear molecule, both of the two independent Sn atoms are five-coordinated, with distorted trigonal–bipyramidal SnC(2)O(3) geometries. One Sn atom is coordinated by two butyl groups, one O atom of the benzoate anion and two bridging O atoms, whereas the other Sn atom is coordinated by two butyl groups, two O atoms of the benzoate anions and a bridging O atom. All the butyl groups are equatorial with respect to the SnO(3) trigonal plane. Weak intramolecular C—H⋯O hydrogen bonds stabilize the molecular structures. In one molecule, two of the butyl groups and the bridging benzoate anion are each disordered over two positions. |
format | Online Article Text |
id | pubmed-3212114 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32121142011-11-16 Octabutylbis[μ(2)-4-(diethylamino)benzoato-κ(2) O:O′]bis[4-(diethylamino)benzoato-κO]di-μ(3)-oxido-tetratin(IV) Win, Yip-Foo Choong, Chen-Shang Ha, Sie-Tiong Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Sn(4)(C(4)H(9))(8)(C(11)H(14)NO(2))(4)O(2)], consists of two crystallographically independent half-molecules. The other halves are generated by crystallographic inversion centers. In each tetranuclear molecule, both of the two independent Sn atoms are five-coordinated, with distorted trigonal–bipyramidal SnC(2)O(3) geometries. One Sn atom is coordinated by two butyl groups, one O atom of the benzoate anion and two bridging O atoms, whereas the other Sn atom is coordinated by two butyl groups, two O atoms of the benzoate anions and a bridging O atom. All the butyl groups are equatorial with respect to the SnO(3) trigonal plane. Weak intramolecular C—H⋯O hydrogen bonds stabilize the molecular structures. In one molecule, two of the butyl groups and the bridging benzoate anion are each disordered over two positions. International Union of Crystallography 2011-07-02 /pmc/articles/PMC3212114/ /pubmed/22090816 http://dx.doi.org/10.1107/S1600536811025360 Text en © Win et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Win, Yip-Foo Choong, Chen-Shang Ha, Sie-Tiong Yeap, Chin Sing Fun, Hoong-Kun Octabutylbis[μ(2)-4-(diethylamino)benzoato-κ(2) O:O′]bis[4-(diethylamino)benzoato-κO]di-μ(3)-oxido-tetratin(IV) |
title | Octabutylbis[μ(2)-4-(diethylamino)benzoato-κ(2)
O:O′]bis[4-(diethylamino)benzoato-κO]di-μ(3)-oxido-tetratin(IV) |
title_full | Octabutylbis[μ(2)-4-(diethylamino)benzoato-κ(2)
O:O′]bis[4-(diethylamino)benzoato-κO]di-μ(3)-oxido-tetratin(IV) |
title_fullStr | Octabutylbis[μ(2)-4-(diethylamino)benzoato-κ(2)
O:O′]bis[4-(diethylamino)benzoato-κO]di-μ(3)-oxido-tetratin(IV) |
title_full_unstemmed | Octabutylbis[μ(2)-4-(diethylamino)benzoato-κ(2)
O:O′]bis[4-(diethylamino)benzoato-κO]di-μ(3)-oxido-tetratin(IV) |
title_short | Octabutylbis[μ(2)-4-(diethylamino)benzoato-κ(2)
O:O′]bis[4-(diethylamino)benzoato-κO]di-μ(3)-oxido-tetratin(IV) |
title_sort | octabutylbis[μ(2)-4-(diethylamino)benzoato-κ(2)
o:o′]bis[4-(diethylamino)benzoato-κo]di-μ(3)-oxido-tetratin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212114/ https://www.ncbi.nlm.nih.gov/pubmed/22090816 http://dx.doi.org/10.1107/S1600536811025360 |
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