[Bis(3-amino­prop­yl)amine-κ(3) N,N′,N′′]bis­(thio­cyanato-κN)cobalt(II)

The asymmetric unit of the title compound, [Co(NCS)(2)(C(6)H(17)N(3))], consists of one Co(2+) cation, two thio­cyanate anions and one bis­(3-amino­prop­yl)amine ligand, all in general positions. The cobalt cation is coordinated by five N atoms of two terminal N-bonded thio­cyanate anions and one bi...

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Detalles Bibliográficos
Autores principales: Boeckmann, Jan, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212118/
https://www.ncbi.nlm.nih.gov/pubmed/22090820
http://dx.doi.org/10.1107/S1600536811025876
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author Boeckmann, Jan
Näther, Christian
author_facet Boeckmann, Jan
Näther, Christian
author_sort Boeckmann, Jan
collection PubMed
description The asymmetric unit of the title compound, [Co(NCS)(2)(C(6)H(17)N(3))], consists of one Co(2+) cation, two thio­cyanate anions and one bis­(3-amino­prop­yl)amine ligand, all in general positions. The cobalt cation is coordinated by five N atoms of two terminal N-bonded thio­cyanate anions and one bis­(3-amino­prop­yl)amine ligand, defining a slightly distorted square-pyramidal coordination polyhedron. The mol­ecules are held together in the crystal by weak N—H⋯S inter­actions.
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spelling pubmed-32121182011-11-16 [Bis(3-amino­prop­yl)amine-κ(3) N,N′,N′′]bis­(thio­cyanato-κN)cobalt(II) Boeckmann, Jan Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Co(NCS)(2)(C(6)H(17)N(3))], consists of one Co(2+) cation, two thio­cyanate anions and one bis­(3-amino­prop­yl)amine ligand, all in general positions. The cobalt cation is coordinated by five N atoms of two terminal N-bonded thio­cyanate anions and one bis­(3-amino­prop­yl)amine ligand, defining a slightly distorted square-pyramidal coordination polyhedron. The mol­ecules are held together in the crystal by weak N—H⋯S inter­actions. International Union of Crystallography 2011-07-06 /pmc/articles/PMC3212118/ /pubmed/22090820 http://dx.doi.org/10.1107/S1600536811025876 Text en © Boeckmann and Näther 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Boeckmann, Jan
Näther, Christian
[Bis(3-amino­prop­yl)amine-κ(3) N,N′,N′′]bis­(thio­cyanato-κN)cobalt(II)
title [Bis(3-amino­prop­yl)amine-κ(3) N,N′,N′′]bis­(thio­cyanato-κN)cobalt(II)
title_full [Bis(3-amino­prop­yl)amine-κ(3) N,N′,N′′]bis­(thio­cyanato-κN)cobalt(II)
title_fullStr [Bis(3-amino­prop­yl)amine-κ(3) N,N′,N′′]bis­(thio­cyanato-κN)cobalt(II)
title_full_unstemmed [Bis(3-amino­prop­yl)amine-κ(3) N,N′,N′′]bis­(thio­cyanato-κN)cobalt(II)
title_short [Bis(3-amino­prop­yl)amine-κ(3) N,N′,N′′]bis­(thio­cyanato-κN)cobalt(II)
title_sort [bis(3-amino­prop­yl)amine-κ(3) n,n′,n′′]bis­(thio­cyanato-κn)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212118/
https://www.ncbi.nlm.nih.gov/pubmed/22090820
http://dx.doi.org/10.1107/S1600536811025876
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