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Dichlorido{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3) N,N′,N′′}zinc
The asymmetric unit of the title compound, [ZnCl(2)(C(11)H(17)N(3))], contains two independent pentacoordinate Zn(II) complex molecules. In each molecule, the metal atom is coordinated by an N,N′,N′′-tridenate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. The two molecul...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212119/ https://www.ncbi.nlm.nih.gov/pubmed/22090821 http://dx.doi.org/10.1107/S1600536811025669 |
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author | Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah |
author_facet | Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah |
author_sort | Suleiman Gwaram, Nura |
collection | PubMed |
description | The asymmetric unit of the title compound, [ZnCl(2)(C(11)H(17)N(3))], contains two independent pentacoordinate Zn(II) complex molecules. In each molecule, the metal atom is coordinated by an N,N′,N′′-tridenate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. The two molecules differ little in their geometry, but more in their intermolecular interactions. In the crystal, adjacent molecules are connected via C—H⋯Cl interactions into a three-dimensional supramolecular structure. The network is supplemented by π–π interactions formed between the aromatic rings of pairs of the symmetry-related molecules [centroid–centroid distances = 3.6255 (10) and 3.7073 (10) Å]. The crystal lattice contains void spaces with a size of 52 Å(3). |
format | Online Article Text |
id | pubmed-3212119 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32121192011-11-16 Dichlorido{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3) N,N′,N′′}zinc Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [ZnCl(2)(C(11)H(17)N(3))], contains two independent pentacoordinate Zn(II) complex molecules. In each molecule, the metal atom is coordinated by an N,N′,N′′-tridenate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. The two molecules differ little in their geometry, but more in their intermolecular interactions. In the crystal, adjacent molecules are connected via C—H⋯Cl interactions into a three-dimensional supramolecular structure. The network is supplemented by π–π interactions formed between the aromatic rings of pairs of the symmetry-related molecules [centroid–centroid distances = 3.6255 (10) and 3.7073 (10) Å]. The crystal lattice contains void spaces with a size of 52 Å(3). International Union of Crystallography 2011-07-06 /pmc/articles/PMC3212119/ /pubmed/22090821 http://dx.doi.org/10.1107/S1600536811025669 Text en © Suleiman Gwaram et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah Dichlorido{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3) N,N′,N′′}zinc |
title | Dichlorido{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}zinc |
title_full | Dichlorido{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}zinc |
title_fullStr | Dichlorido{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}zinc |
title_full_unstemmed | Dichlorido{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}zinc |
title_short | Dichlorido{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}zinc |
title_sort | dichlorido{n,n-dimethyl-n′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3)
n,n′,n′′}zinc |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212119/ https://www.ncbi.nlm.nih.gov/pubmed/22090821 http://dx.doi.org/10.1107/S1600536811025669 |
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