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Dichlorido{N,N-dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}zinc

The asymmetric unit of the title compound, [ZnCl(2)(C(11)H(17)N(3))], contains two independent penta­coordinate Zn(II) complex mol­ecules. In each mol­ecule, the metal atom is coordinated by an N,N′,N′′-tridenate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. The two mol­ecul...

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Autores principales: Suleiman Gwaram, Nura, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212119/
https://www.ncbi.nlm.nih.gov/pubmed/22090821
http://dx.doi.org/10.1107/S1600536811025669
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author Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Suleiman Gwaram, Nura
collection PubMed
description The asymmetric unit of the title compound, [ZnCl(2)(C(11)H(17)N(3))], contains two independent penta­coordinate Zn(II) complex mol­ecules. In each mol­ecule, the metal atom is coordinated by an N,N′,N′′-tridenate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. The two mol­ecules differ little in their geometry, but more in their inter­molecular inter­actions. In the crystal, adjacent mol­ecules are connected via C—H⋯Cl inter­actions into a three-dimensional supra­molecular structure. The network is supplemented by π–π inter­actions formed between the aromatic rings of pairs of the symmetry-related mol­ecules [centroid–centroid distances = 3.6255 (10) and 3.7073 (10) Å]. The crystal lattice contains void spaces with a size of 52 Å(3).
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spelling pubmed-32121192011-11-16 Dichlorido{N,N-dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}zinc Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [ZnCl(2)(C(11)H(17)N(3))], contains two independent penta­coordinate Zn(II) complex mol­ecules. In each mol­ecule, the metal atom is coordinated by an N,N′,N′′-tridenate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. The two mol­ecules differ little in their geometry, but more in their inter­molecular inter­actions. In the crystal, adjacent mol­ecules are connected via C—H⋯Cl inter­actions into a three-dimensional supra­molecular structure. The network is supplemented by π–π inter­actions formed between the aromatic rings of pairs of the symmetry-related mol­ecules [centroid–centroid distances = 3.6255 (10) and 3.7073 (10) Å]. The crystal lattice contains void spaces with a size of 52 Å(3). International Union of Crystallography 2011-07-06 /pmc/articles/PMC3212119/ /pubmed/22090821 http://dx.doi.org/10.1107/S1600536811025669 Text en © Suleiman Gwaram et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
Dichlorido{N,N-dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}zinc
title Dichlorido{N,N-dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}zinc
title_full Dichlorido{N,N-dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}zinc
title_fullStr Dichlorido{N,N-dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}zinc
title_full_unstemmed Dichlorido{N,N-dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}zinc
title_short Dichlorido{N,N-dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}zinc
title_sort dichlorido{n,n-dimethyl-n′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) n,n′,n′′}zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212119/
https://www.ncbi.nlm.nih.gov/pubmed/22090821
http://dx.doi.org/10.1107/S1600536811025669
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