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[5-Chloro-2-hydroxy-N′-(2-oxidobenzylidene)benzohydrazidato]dimethyltin(IV)
In the title compound, [Sn(CH(3))(2)(C(14)H(9)ClN(2)O(3))], the Sn(IV) ion is coordinated by one N and two O atoms from the tridentate 5-chloro-2-hydroxy-N′-(2-oxidobenzylidene)benzohydrazidate (L) ligand and two methyl groups in a distorted trigonal–bipyramidal geometry. In the ligand, the hydro...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212120/ https://www.ncbi.nlm.nih.gov/pubmed/22090822 http://dx.doi.org/10.1107/S1600536811025621 |
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author | Zhang, Xiuyun Yue, Caihong Yin, Handong |
author_facet | Zhang, Xiuyun Yue, Caihong Yin, Handong |
author_sort | Zhang, Xiuyun |
collection | PubMed |
description | In the title compound, [Sn(CH(3))(2)(C(14)H(9)ClN(2)O(3))], the Sn(IV) ion is coordinated by one N and two O atoms from the tridentate 5-chloro-2-hydroxy-N′-(2-oxidobenzylidene)benzohydrazidate (L) ligand and two methyl groups in a distorted trigonal–bipyramidal geometry. In the ligand, the hydroxy group is involved in an intramolecular O—H⋯N hydrogen bond and the two aromatic rings form a dihedral angle of 5.5 (1)°. In the crystal, weak intermolecular C—H⋯O hydrogen bonds and π–π interactions between the aromatic rings [centroid–centroid distance = 3.816 (3) Å] link the molecules into centrosymmetric dimers. |
format | Online Article Text |
id | pubmed-3212120 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32121202011-11-16 [5-Chloro-2-hydroxy-N′-(2-oxidobenzylidene)benzohydrazidato]dimethyltin(IV) Zhang, Xiuyun Yue, Caihong Yin, Handong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sn(CH(3))(2)(C(14)H(9)ClN(2)O(3))], the Sn(IV) ion is coordinated by one N and two O atoms from the tridentate 5-chloro-2-hydroxy-N′-(2-oxidobenzylidene)benzohydrazidate (L) ligand and two methyl groups in a distorted trigonal–bipyramidal geometry. In the ligand, the hydroxy group is involved in an intramolecular O—H⋯N hydrogen bond and the two aromatic rings form a dihedral angle of 5.5 (1)°. In the crystal, weak intermolecular C—H⋯O hydrogen bonds and π–π interactions between the aromatic rings [centroid–centroid distance = 3.816 (3) Å] link the molecules into centrosymmetric dimers. International Union of Crystallography 2011-07-06 /pmc/articles/PMC3212120/ /pubmed/22090822 http://dx.doi.org/10.1107/S1600536811025621 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Xiuyun Yue, Caihong Yin, Handong [5-Chloro-2-hydroxy-N′-(2-oxidobenzylidene)benzohydrazidato]dimethyltin(IV) |
title | [5-Chloro-2-hydroxy-N′-(2-oxidobenzylidene)benzohydrazidato]dimethyltin(IV) |
title_full | [5-Chloro-2-hydroxy-N′-(2-oxidobenzylidene)benzohydrazidato]dimethyltin(IV) |
title_fullStr | [5-Chloro-2-hydroxy-N′-(2-oxidobenzylidene)benzohydrazidato]dimethyltin(IV) |
title_full_unstemmed | [5-Chloro-2-hydroxy-N′-(2-oxidobenzylidene)benzohydrazidato]dimethyltin(IV) |
title_short | [5-Chloro-2-hydroxy-N′-(2-oxidobenzylidene)benzohydrazidato]dimethyltin(IV) |
title_sort | [5-chloro-2-hydroxy-n′-(2-oxidobenzylidene)benzohydrazidato]dimethyltin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212120/ https://www.ncbi.nlm.nih.gov/pubmed/22090822 http://dx.doi.org/10.1107/S1600536811025621 |
work_keys_str_mv | AT zhangxiuyun 5chloro2hydroxyn2oxidobenzylidenebenzohydrazidatodimethyltiniv AT yuecaihong 5chloro2hydroxyn2oxidobenzylidenebenzohydrazidatodimethyltiniv AT yinhandong 5chloro2hydroxyn2oxidobenzylidenebenzohydrazidatodimethyltiniv |