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[5-Chloro-2-hy­droxy-N′-(2-oxidobenzyl­idene)benzohydrazidato]dimethyl­tin(IV)

In the title compound, [Sn(CH(3))(2)(C(14)H(9)ClN(2)O(3))], the Sn(IV) ion is coordinated by one N and two O atoms from the tridentate 5-chloro-2-hy­droxy-N′-(2-oxidobenzyl­idene)benzohydrazidate (L) ligand and two methyl groups in a distorted trigonal–bipyramidal geometry. In the ligand, the hy­dro...

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Autores principales: Zhang, Xiuyun, Yue, Caihong, Yin, Handong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212120/
https://www.ncbi.nlm.nih.gov/pubmed/22090822
http://dx.doi.org/10.1107/S1600536811025621
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author Zhang, Xiuyun
Yue, Caihong
Yin, Handong
author_facet Zhang, Xiuyun
Yue, Caihong
Yin, Handong
author_sort Zhang, Xiuyun
collection PubMed
description In the title compound, [Sn(CH(3))(2)(C(14)H(9)ClN(2)O(3))], the Sn(IV) ion is coordinated by one N and two O atoms from the tridentate 5-chloro-2-hy­droxy-N′-(2-oxidobenzyl­idene)benzohydrazidate (L) ligand and two methyl groups in a distorted trigonal–bipyramidal geometry. In the ligand, the hy­droxy group is involved in an intra­molecular O—H⋯N hydrogen bond and the two aromatic rings form a dihedral angle of 5.5 (1)°. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds and π–π inter­actions between the aromatic rings [centroid–centroid distance = 3.816 (3) Å] link the mol­ecules into centrosymmetric dimers.
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spelling pubmed-32121202011-11-16 [5-Chloro-2-hy­droxy-N′-(2-oxidobenzyl­idene)benzohydrazidato]dimethyl­tin(IV) Zhang, Xiuyun Yue, Caihong Yin, Handong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sn(CH(3))(2)(C(14)H(9)ClN(2)O(3))], the Sn(IV) ion is coordinated by one N and two O atoms from the tridentate 5-chloro-2-hy­droxy-N′-(2-oxidobenzyl­idene)benzohydrazidate (L) ligand and two methyl groups in a distorted trigonal–bipyramidal geometry. In the ligand, the hy­droxy group is involved in an intra­molecular O—H⋯N hydrogen bond and the two aromatic rings form a dihedral angle of 5.5 (1)°. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds and π–π inter­actions between the aromatic rings [centroid–centroid distance = 3.816 (3) Å] link the mol­ecules into centrosymmetric dimers. International Union of Crystallography 2011-07-06 /pmc/articles/PMC3212120/ /pubmed/22090822 http://dx.doi.org/10.1107/S1600536811025621 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Xiuyun
Yue, Caihong
Yin, Handong
[5-Chloro-2-hy­droxy-N′-(2-oxidobenzyl­idene)benzohydrazidato]dimethyl­tin(IV)
title [5-Chloro-2-hy­droxy-N′-(2-oxidobenzyl­idene)benzohydrazidato]dimethyl­tin(IV)
title_full [5-Chloro-2-hy­droxy-N′-(2-oxidobenzyl­idene)benzohydrazidato]dimethyl­tin(IV)
title_fullStr [5-Chloro-2-hy­droxy-N′-(2-oxidobenzyl­idene)benzohydrazidato]dimethyl­tin(IV)
title_full_unstemmed [5-Chloro-2-hy­droxy-N′-(2-oxidobenzyl­idene)benzohydrazidato]dimethyl­tin(IV)
title_short [5-Chloro-2-hy­droxy-N′-(2-oxidobenzyl­idene)benzohydrazidato]dimethyl­tin(IV)
title_sort [5-chloro-2-hy­droxy-n′-(2-oxidobenzyl­idene)benzohydrazidato]dimethyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212120/
https://www.ncbi.nlm.nih.gov/pubmed/22090822
http://dx.doi.org/10.1107/S1600536811025621
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AT yinhandong 5chloro2hydroxyn2oxidobenzylidenebenzohydrazidatodimethyltiniv