catena-Poly[[trimethyl­tin(IV)]-μ-3,5-difluoro­benzoato-κ(2) O:O′]

In the title compound, [Sn(CH(3))(3)(C(7)H(3)F(2)O(2))](n), the central Sn atom is coordinated by two O atoms from the anion and three methyl C atoms in a polymeric fashion owing to the presence of bidentate bridging carboxyl­ate ligands. The five-coordinate Sn atom exists in a distorted trigonal–bi...

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Detalles Bibliográficos
Autores principales: Liu, Hong, Yin, Handong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212122/
https://www.ncbi.nlm.nih.gov/pubmed/22090824
http://dx.doi.org/10.1107/S1600536811025608
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author Liu, Hong
Yin, Handong
author_facet Liu, Hong
Yin, Handong
author_sort Liu, Hong
collection PubMed
description In the title compound, [Sn(CH(3))(3)(C(7)H(3)F(2)O(2))](n), the central Sn atom is coordinated by two O atoms from the anion and three methyl C atoms in a polymeric fashion owing to the presence of bidentate bridging carboxyl­ate ligands. The five-coordinate Sn atom exists in a distorted trigonal–bipyramidal geometry with the mol­ecules connected by weak C—H⋯F inter­moleclar inter­actions, forming supra­molecular chains parallel to [010].
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spelling pubmed-32121222011-11-16 catena-Poly[[trimethyl­tin(IV)]-μ-3,5-difluoro­benzoato-κ(2) O:O′] Liu, Hong Yin, Handong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sn(CH(3))(3)(C(7)H(3)F(2)O(2))](n), the central Sn atom is coordinated by two O atoms from the anion and three methyl C atoms in a polymeric fashion owing to the presence of bidentate bridging carboxyl­ate ligands. The five-coordinate Sn atom exists in a distorted trigonal–bipyramidal geometry with the mol­ecules connected by weak C—H⋯F inter­moleclar inter­actions, forming supra­molecular chains parallel to [010]. International Union of Crystallography 2011-07-06 /pmc/articles/PMC3212122/ /pubmed/22090824 http://dx.doi.org/10.1107/S1600536811025608 Text en © Liu and Yin 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Hong
Yin, Handong
catena-Poly[[trimethyl­tin(IV)]-μ-3,5-difluoro­benzoato-κ(2) O:O′]
title catena-Poly[[trimethyl­tin(IV)]-μ-3,5-difluoro­benzoato-κ(2) O:O′]
title_full catena-Poly[[trimethyl­tin(IV)]-μ-3,5-difluoro­benzoato-κ(2) O:O′]
title_fullStr catena-Poly[[trimethyl­tin(IV)]-μ-3,5-difluoro­benzoato-κ(2) O:O′]
title_full_unstemmed catena-Poly[[trimethyl­tin(IV)]-μ-3,5-difluoro­benzoato-κ(2) O:O′]
title_short catena-Poly[[trimethyl­tin(IV)]-μ-3,5-difluoro­benzoato-κ(2) O:O′]
title_sort catena-poly[[trimethyl­tin(iv)]-μ-3,5-difluoro­benzoato-κ(2) o:o′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212122/
https://www.ncbi.nlm.nih.gov/pubmed/22090824
http://dx.doi.org/10.1107/S1600536811025608
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