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Poly[[μ-1,4-bis­(1H-imidazol-4-yl)benzene-κ(2) N (3):N (3′)](μ-5-methyl­isophthalato-κ(2) O (1):O (3))cobalt(II)]

In the title coordination polymer, [Co(C(9)H(6)O(4))(C(12)H(10)N(4))](n), the Co(II) atom is four-coordinated by two O atoms from two different 5-methyl­isophthalate bivalent anions and two N atoms from two different 1,4-bis­(1H-imidazol-4-yl)benzene ligands, forming a four-coordinated tetra­hedral...

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Detalles Bibliográficos
Autores principales: Chen, Shui-Sheng, Yang, Sen-Lin, Zhang, Shu-Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212123/
https://www.ncbi.nlm.nih.gov/pubmed/22090825
http://dx.doi.org/10.1107/S1600536811025657
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author Chen, Shui-Sheng
Yang, Sen-Lin
Zhang, Shu-Ping
author_facet Chen, Shui-Sheng
Yang, Sen-Lin
Zhang, Shu-Ping
author_sort Chen, Shui-Sheng
collection PubMed
description In the title coordination polymer, [Co(C(9)H(6)O(4))(C(12)H(10)N(4))](n), the Co(II) atom is four-coordinated by two O atoms from two different 5-methyl­isophthalate bivalent anions and two N atoms from two different 1,4-bis­(1H-imidazol-4-yl)benzene ligands, forming a four-coordinated tetra­hedral coordination geometry. Each 5-methyl­isophthalate ligand acts as a μ(2)-bridge, linking two Co(II) atoms and forming chains which are further linked by 1,4-bis­(1H-imidazol-4-yl)benzene ligands into a two-dimensional network parallel to ([Image: see text]01). These planes are, in turn, linked by two inter­molecular N—H⋯O inter­actions, forming a three-dimensional structure. Weak C—H⋯O hydrogen bonds are also present in the structure.
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spelling pubmed-32121232011-11-16 Poly[[μ-1,4-bis­(1H-imidazol-4-yl)benzene-κ(2) N (3):N (3′)](μ-5-methyl­isophthalato-κ(2) O (1):O (3))cobalt(II)] Chen, Shui-Sheng Yang, Sen-Lin Zhang, Shu-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Co(C(9)H(6)O(4))(C(12)H(10)N(4))](n), the Co(II) atom is four-coordinated by two O atoms from two different 5-methyl­isophthalate bivalent anions and two N atoms from two different 1,4-bis­(1H-imidazol-4-yl)benzene ligands, forming a four-coordinated tetra­hedral coordination geometry. Each 5-methyl­isophthalate ligand acts as a μ(2)-bridge, linking two Co(II) atoms and forming chains which are further linked by 1,4-bis­(1H-imidazol-4-yl)benzene ligands into a two-dimensional network parallel to ([Image: see text]01). These planes are, in turn, linked by two inter­molecular N—H⋯O inter­actions, forming a three-dimensional structure. Weak C—H⋯O hydrogen bonds are also present in the structure. International Union of Crystallography 2011-07-06 /pmc/articles/PMC3212123/ /pubmed/22090825 http://dx.doi.org/10.1107/S1600536811025657 Text en © Chen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Shui-Sheng
Yang, Sen-Lin
Zhang, Shu-Ping
Poly[[μ-1,4-bis­(1H-imidazol-4-yl)benzene-κ(2) N (3):N (3′)](μ-5-methyl­isophthalato-κ(2) O (1):O (3))cobalt(II)]
title Poly[[μ-1,4-bis­(1H-imidazol-4-yl)benzene-κ(2) N (3):N (3′)](μ-5-methyl­isophthalato-κ(2) O (1):O (3))cobalt(II)]
title_full Poly[[μ-1,4-bis­(1H-imidazol-4-yl)benzene-κ(2) N (3):N (3′)](μ-5-methyl­isophthalato-κ(2) O (1):O (3))cobalt(II)]
title_fullStr Poly[[μ-1,4-bis­(1H-imidazol-4-yl)benzene-κ(2) N (3):N (3′)](μ-5-methyl­isophthalato-κ(2) O (1):O (3))cobalt(II)]
title_full_unstemmed Poly[[μ-1,4-bis­(1H-imidazol-4-yl)benzene-κ(2) N (3):N (3′)](μ-5-methyl­isophthalato-κ(2) O (1):O (3))cobalt(II)]
title_short Poly[[μ-1,4-bis­(1H-imidazol-4-yl)benzene-κ(2) N (3):N (3′)](μ-5-methyl­isophthalato-κ(2) O (1):O (3))cobalt(II)]
title_sort poly[[μ-1,4-bis­(1h-imidazol-4-yl)benzene-κ(2) n (3):n (3′)](μ-5-methyl­isophthalato-κ(2) o (1):o (3))cobalt(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212123/
https://www.ncbi.nlm.nih.gov/pubmed/22090825
http://dx.doi.org/10.1107/S1600536811025657
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