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Poly[[μ-1,4-bis(1H-imidazol-4-yl)benzene-κ(2) N (3):N (3′)](μ-5-methylisophthalato-κ(2) O (1):O (3))cobalt(II)]
In the title coordination polymer, [Co(C(9)H(6)O(4))(C(12)H(10)N(4))](n), the Co(II) atom is four-coordinated by two O atoms from two different 5-methylisophthalate bivalent anions and two N atoms from two different 1,4-bis(1H-imidazol-4-yl)benzene ligands, forming a four-coordinated tetrahedral...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212123/ https://www.ncbi.nlm.nih.gov/pubmed/22090825 http://dx.doi.org/10.1107/S1600536811025657 |
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author | Chen, Shui-Sheng Yang, Sen-Lin Zhang, Shu-Ping |
author_facet | Chen, Shui-Sheng Yang, Sen-Lin Zhang, Shu-Ping |
author_sort | Chen, Shui-Sheng |
collection | PubMed |
description | In the title coordination polymer, [Co(C(9)H(6)O(4))(C(12)H(10)N(4))](n), the Co(II) atom is four-coordinated by two O atoms from two different 5-methylisophthalate bivalent anions and two N atoms from two different 1,4-bis(1H-imidazol-4-yl)benzene ligands, forming a four-coordinated tetrahedral coordination geometry. Each 5-methylisophthalate ligand acts as a μ(2)-bridge, linking two Co(II) atoms and forming chains which are further linked by 1,4-bis(1H-imidazol-4-yl)benzene ligands into a two-dimensional network parallel to ([Image: see text]01). These planes are, in turn, linked by two intermolecular N—H⋯O interactions, forming a three-dimensional structure. Weak C—H⋯O hydrogen bonds are also present in the structure. |
format | Online Article Text |
id | pubmed-3212123 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32121232011-11-16 Poly[[μ-1,4-bis(1H-imidazol-4-yl)benzene-κ(2) N (3):N (3′)](μ-5-methylisophthalato-κ(2) O (1):O (3))cobalt(II)] Chen, Shui-Sheng Yang, Sen-Lin Zhang, Shu-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Co(C(9)H(6)O(4))(C(12)H(10)N(4))](n), the Co(II) atom is four-coordinated by two O atoms from two different 5-methylisophthalate bivalent anions and two N atoms from two different 1,4-bis(1H-imidazol-4-yl)benzene ligands, forming a four-coordinated tetrahedral coordination geometry. Each 5-methylisophthalate ligand acts as a μ(2)-bridge, linking two Co(II) atoms and forming chains which are further linked by 1,4-bis(1H-imidazol-4-yl)benzene ligands into a two-dimensional network parallel to ([Image: see text]01). These planes are, in turn, linked by two intermolecular N—H⋯O interactions, forming a three-dimensional structure. Weak C—H⋯O hydrogen bonds are also present in the structure. International Union of Crystallography 2011-07-06 /pmc/articles/PMC3212123/ /pubmed/22090825 http://dx.doi.org/10.1107/S1600536811025657 Text en © Chen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Chen, Shui-Sheng Yang, Sen-Lin Zhang, Shu-Ping Poly[[μ-1,4-bis(1H-imidazol-4-yl)benzene-κ(2) N (3):N (3′)](μ-5-methylisophthalato-κ(2) O (1):O (3))cobalt(II)] |
title | Poly[[μ-1,4-bis(1H-imidazol-4-yl)benzene-κ(2)
N
(3):N
(3′)](μ-5-methylisophthalato-κ(2)
O
(1):O
(3))cobalt(II)] |
title_full | Poly[[μ-1,4-bis(1H-imidazol-4-yl)benzene-κ(2)
N
(3):N
(3′)](μ-5-methylisophthalato-κ(2)
O
(1):O
(3))cobalt(II)] |
title_fullStr | Poly[[μ-1,4-bis(1H-imidazol-4-yl)benzene-κ(2)
N
(3):N
(3′)](μ-5-methylisophthalato-κ(2)
O
(1):O
(3))cobalt(II)] |
title_full_unstemmed | Poly[[μ-1,4-bis(1H-imidazol-4-yl)benzene-κ(2)
N
(3):N
(3′)](μ-5-methylisophthalato-κ(2)
O
(1):O
(3))cobalt(II)] |
title_short | Poly[[μ-1,4-bis(1H-imidazol-4-yl)benzene-κ(2)
N
(3):N
(3′)](μ-5-methylisophthalato-κ(2)
O
(1):O
(3))cobalt(II)] |
title_sort | poly[[μ-1,4-bis(1h-imidazol-4-yl)benzene-κ(2)
n
(3):n
(3′)](μ-5-methylisophthalato-κ(2)
o
(1):o
(3))cobalt(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212123/ https://www.ncbi.nlm.nih.gov/pubmed/22090825 http://dx.doi.org/10.1107/S1600536811025657 |
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