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Bis{4-bromo-2-[(2-hydroxyethyl)iminomethyl]phenolato-κ(3) O,N,O′}cadmium
The centrosymmetric title compound, [Cd(C(9)H(9)BrNO(2))(2)], was obtained by the reaction of 5-bromosalicylaldehyde, 2-aminoethanol and cadmium nitrate in ethanol. The Cd atom, located on an inversion centre, is hexacoordinated by two Schiff base ligands in an octahedral coordination through t...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212126/ https://www.ncbi.nlm.nih.gov/pubmed/22090828 http://dx.doi.org/10.1107/S1600536811025852 |
| _version_ | 1782215924294615040 |
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| author | Yu, Jing |
| author_facet | Yu, Jing |
| author_sort | Yu, Jing |
| collection | PubMed |
| description | The centrosymmetric title compound, [Cd(C(9)H(9)BrNO(2))(2)], was obtained by the reaction of 5-bromosalicylaldehyde, 2-aminoethanol and cadmium nitrate in ethanol. The Cd atom, located on an inversion centre, is hexacoordinated by two Schiff base ligands in an octahedral coordination through the phenolate O atom, the imine N atom and the hydroxy O atoms. In the crystal, molecules are linked through intermolecular O—H⋯O hydrogen bonds, forming chains along the b axis. |
| format | Online Article Text |
| id | pubmed-3212126 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32121262011-11-16 Bis{4-bromo-2-[(2-hydroxyethyl)iminomethyl]phenolato-κ(3) O,N,O′}cadmium Yu, Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The centrosymmetric title compound, [Cd(C(9)H(9)BrNO(2))(2)], was obtained by the reaction of 5-bromosalicylaldehyde, 2-aminoethanol and cadmium nitrate in ethanol. The Cd atom, located on an inversion centre, is hexacoordinated by two Schiff base ligands in an octahedral coordination through the phenolate O atom, the imine N atom and the hydroxy O atoms. In the crystal, molecules are linked through intermolecular O—H⋯O hydrogen bonds, forming chains along the b axis. International Union of Crystallography 2011-07-06 /pmc/articles/PMC3212126/ /pubmed/22090828 http://dx.doi.org/10.1107/S1600536811025852 Text en © Jing Yu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Yu, Jing Bis{4-bromo-2-[(2-hydroxyethyl)iminomethyl]phenolato-κ(3) O,N,O′}cadmium |
| title | Bis{4-bromo-2-[(2-hydroxyethyl)iminomethyl]phenolato-κ(3)
O,N,O′}cadmium |
| title_full | Bis{4-bromo-2-[(2-hydroxyethyl)iminomethyl]phenolato-κ(3)
O,N,O′}cadmium |
| title_fullStr | Bis{4-bromo-2-[(2-hydroxyethyl)iminomethyl]phenolato-κ(3)
O,N,O′}cadmium |
| title_full_unstemmed | Bis{4-bromo-2-[(2-hydroxyethyl)iminomethyl]phenolato-κ(3)
O,N,O′}cadmium |
| title_short | Bis{4-bromo-2-[(2-hydroxyethyl)iminomethyl]phenolato-κ(3)
O,N,O′}cadmium |
| title_sort | bis{4-bromo-2-[(2-hydroxyethyl)iminomethyl]phenolato-κ(3)
o,n,o′}cadmium |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212126/ https://www.ncbi.nlm.nih.gov/pubmed/22090828 http://dx.doi.org/10.1107/S1600536811025852 |
| work_keys_str_mv | AT yujing bis4bromo22hydroxyethyliminomethylphenolatok3onocadmium |