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Bis{N-methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine}zinc bis(perchlorate)
The title mononuclear zinc(II) complex, [Zn(C(10)H(15)N(3))(2)](ClO(4))(2), was obtained by the reaction of 2-acetylpyridine, N-methylethane-1,2-diamine and zinc perchlorate in methanol. The asymmetric unit of the complex contains two independent [Zn(C(10)H(15)N(3))(2)](2+) cations and four perchl...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212129/ https://www.ncbi.nlm.nih.gov/pubmed/22090831 http://dx.doi.org/10.1107/S1600536811026079 |
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author | Wang, Chen-Yi |
author_facet | Wang, Chen-Yi |
author_sort | Wang, Chen-Yi |
collection | PubMed |
description | The title mononuclear zinc(II) complex, [Zn(C(10)H(15)N(3))(2)](ClO(4))(2), was obtained by the reaction of 2-acetylpyridine, N-methylethane-1,2-diamine and zinc perchlorate in methanol. The asymmetric unit of the complex contains two independent [Zn(C(10)H(15)N(3))(2)](2+) cations and four perchlorate anions. The Zn(II) atom in each complex cation is six-coordinated by two pyridine N, two imine N and two amine N atoms from two N-methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine Schiff base ligands in a distorted octahedral geometry. The pyridine rings in each of the complex cations are approximately perpendicular to each other, making dihedral angles of 88.4 (3) and 87.9 (3)°. The perchlorate anions are linked to the complex cations through N—H⋯O hydrogen bonds |
format | Online Article Text |
id | pubmed-3212129 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32121292011-11-16 Bis{N-methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine}zinc bis(perchlorate) Wang, Chen-Yi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mononuclear zinc(II) complex, [Zn(C(10)H(15)N(3))(2)](ClO(4))(2), was obtained by the reaction of 2-acetylpyridine, N-methylethane-1,2-diamine and zinc perchlorate in methanol. The asymmetric unit of the complex contains two independent [Zn(C(10)H(15)N(3))(2)](2+) cations and four perchlorate anions. The Zn(II) atom in each complex cation is six-coordinated by two pyridine N, two imine N and two amine N atoms from two N-methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine Schiff base ligands in a distorted octahedral geometry. The pyridine rings in each of the complex cations are approximately perpendicular to each other, making dihedral angles of 88.4 (3) and 87.9 (3)°. The perchlorate anions are linked to the complex cations through N—H⋯O hydrogen bonds International Union of Crystallography 2011-07-06 /pmc/articles/PMC3212129/ /pubmed/22090831 http://dx.doi.org/10.1107/S1600536811026079 Text en © Chen-Yi Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Chen-Yi Bis{N-methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine}zinc bis(perchlorate) |
title | Bis{N-methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine}zinc bis(perchlorate) |
title_full | Bis{N-methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine}zinc bis(perchlorate) |
title_fullStr | Bis{N-methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine}zinc bis(perchlorate) |
title_full_unstemmed | Bis{N-methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine}zinc bis(perchlorate) |
title_short | Bis{N-methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine}zinc bis(perchlorate) |
title_sort | bis{n-methyl-n′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine}zinc bis(perchlorate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212129/ https://www.ncbi.nlm.nih.gov/pubmed/22090831 http://dx.doi.org/10.1107/S1600536811026079 |
work_keys_str_mv | AT wangchenyi bisnmethyln1pyridin2ylethylideneethane12diaminezincbisperchlorate |