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Bis{N-methyl-N′-[1-(pyridin-2-yl)ethyl­idene]ethane-1,2-diamine}­zinc bis­(perchlorate)

The title mononuclear zinc(II) complex, [Zn(C(10)H(15)N(3))(2)](ClO(4))(2), was obtained by the reaction of 2-acetyl­pyridine, N-methyl­ethane-1,2-diamine and zinc perchlorate in methanol. The asymmetric unit of the complex contains two independent [Zn(C(10)H(15)N(3))(2)](2+) cations and four perchl...

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Autor principal: Wang, Chen-Yi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212129/
https://www.ncbi.nlm.nih.gov/pubmed/22090831
http://dx.doi.org/10.1107/S1600536811026079
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author Wang, Chen-Yi
author_facet Wang, Chen-Yi
author_sort Wang, Chen-Yi
collection PubMed
description The title mononuclear zinc(II) complex, [Zn(C(10)H(15)N(3))(2)](ClO(4))(2), was obtained by the reaction of 2-acetyl­pyridine, N-methyl­ethane-1,2-diamine and zinc perchlorate in methanol. The asymmetric unit of the complex contains two independent [Zn(C(10)H(15)N(3))(2)](2+) cations and four perchlorate anions. The Zn(II) atom in each complex cation is six-coordinated by two pyridine N, two imine N and two amine N atoms from two N-methyl-N′-[1-(pyridin-2-yl)ethyl­idene]ethane-1,2-diamine Schiff base ligands in a distorted octa­hedral geometry. The pyridine rings in each of the complex cations are approximately perpendicular to each other, making dihedral angles of 88.4 (3) and 87.9 (3)°. The perchlorate anions are linked to the complex cations through N—H⋯O hydrogen bonds
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spelling pubmed-32121292011-11-16 Bis{N-methyl-N′-[1-(pyridin-2-yl)ethyl­idene]ethane-1,2-diamine}­zinc bis­(perchlorate) Wang, Chen-Yi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mononuclear zinc(II) complex, [Zn(C(10)H(15)N(3))(2)](ClO(4))(2), was obtained by the reaction of 2-acetyl­pyridine, N-methyl­ethane-1,2-diamine and zinc perchlorate in methanol. The asymmetric unit of the complex contains two independent [Zn(C(10)H(15)N(3))(2)](2+) cations and four perchlorate anions. The Zn(II) atom in each complex cation is six-coordinated by two pyridine N, two imine N and two amine N atoms from two N-methyl-N′-[1-(pyridin-2-yl)ethyl­idene]ethane-1,2-diamine Schiff base ligands in a distorted octa­hedral geometry. The pyridine rings in each of the complex cations are approximately perpendicular to each other, making dihedral angles of 88.4 (3) and 87.9 (3)°. The perchlorate anions are linked to the complex cations through N—H⋯O hydrogen bonds International Union of Crystallography 2011-07-06 /pmc/articles/PMC3212129/ /pubmed/22090831 http://dx.doi.org/10.1107/S1600536811026079 Text en © Chen-Yi Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Chen-Yi
Bis{N-methyl-N′-[1-(pyridin-2-yl)ethyl­idene]ethane-1,2-diamine}­zinc bis­(perchlorate)
title Bis{N-methyl-N′-[1-(pyridin-2-yl)ethyl­idene]ethane-1,2-diamine}­zinc bis­(perchlorate)
title_full Bis{N-methyl-N′-[1-(pyridin-2-yl)ethyl­idene]ethane-1,2-diamine}­zinc bis­(perchlorate)
title_fullStr Bis{N-methyl-N′-[1-(pyridin-2-yl)ethyl­idene]ethane-1,2-diamine}­zinc bis­(perchlorate)
title_full_unstemmed Bis{N-methyl-N′-[1-(pyridin-2-yl)ethyl­idene]ethane-1,2-diamine}­zinc bis­(perchlorate)
title_short Bis{N-methyl-N′-[1-(pyridin-2-yl)ethyl­idene]ethane-1,2-diamine}­zinc bis­(perchlorate)
title_sort bis{n-methyl-n′-[1-(pyridin-2-yl)ethyl­idene]ethane-1,2-diamine}­zinc bis­(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212129/
https://www.ncbi.nlm.nih.gov/pubmed/22090831
http://dx.doi.org/10.1107/S1600536811026079
work_keys_str_mv AT wangchenyi bisnmethyln1pyridin2ylethylideneethane12diaminezincbisperchlorate