Poly[(μ-3,5-dinitro­benzoato)(μ-3,5-dinitro­benzoic acid)rubidium]

The asymmetric unit of the title compound, [Rb(C(7)H(3)N(2)O(6))(C(7)H(4)N(2)O(6))](n), comprises an Rb(+) cation, a 3,5-dinitro­benzoate anion and a 3,5-dinitro­benzoic acid ligand. The Rb(+) cation is nine-coordinated by O atoms from four 3,5-dinitro­benzoate anions and three neutral 3,5-dinitro­b...

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Detalles Bibliográficos
Autores principales: Miao, Yanqing, Fan, Tao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212130/
https://www.ncbi.nlm.nih.gov/pubmed/22090832
http://dx.doi.org/10.1107/S160053681102513X
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author Miao, Yanqing
Fan, Tao
author_facet Miao, Yanqing
Fan, Tao
author_sort Miao, Yanqing
collection PubMed
description The asymmetric unit of the title compound, [Rb(C(7)H(3)N(2)O(6))(C(7)H(4)N(2)O(6))](n), comprises an Rb(+) cation, a 3,5-dinitro­benzoate anion and a 3,5-dinitro­benzoic acid ligand. The Rb(+) cation is nine-coordinated by O atoms from four 3,5-dinitro­benzoate anions and three neutral 3,5-dinitro­benzoic acid ligands. The metal atom is firstly linked by four bridging carboxyl groups, forming a binuclear motif, which is further linked by the nitro groups into a two-dimensional framework along the [110] direction. A short O—H⋯O hydrogen bond between two adjacent carboxy/carboxylate groups occurs.
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spelling pubmed-32121302011-11-16 Poly[(μ-3,5-dinitro­benzoato)(μ-3,5-dinitro­benzoic acid)rubidium] Miao, Yanqing Fan, Tao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Rb(C(7)H(3)N(2)O(6))(C(7)H(4)N(2)O(6))](n), comprises an Rb(+) cation, a 3,5-dinitro­benzoate anion and a 3,5-dinitro­benzoic acid ligand. The Rb(+) cation is nine-coordinated by O atoms from four 3,5-dinitro­benzoate anions and three neutral 3,5-dinitro­benzoic acid ligands. The metal atom is firstly linked by four bridging carboxyl groups, forming a binuclear motif, which is further linked by the nitro groups into a two-dimensional framework along the [110] direction. A short O—H⋯O hydrogen bond between two adjacent carboxy/carboxylate groups occurs. International Union of Crystallography 2011-07-06 /pmc/articles/PMC3212130/ /pubmed/22090832 http://dx.doi.org/10.1107/S160053681102513X Text en © Miao amd Fan 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Miao, Yanqing
Fan, Tao
Poly[(μ-3,5-dinitro­benzoato)(μ-3,5-dinitro­benzoic acid)rubidium]
title Poly[(μ-3,5-dinitro­benzoato)(μ-3,5-dinitro­benzoic acid)rubidium]
title_full Poly[(μ-3,5-dinitro­benzoato)(μ-3,5-dinitro­benzoic acid)rubidium]
title_fullStr Poly[(μ-3,5-dinitro­benzoato)(μ-3,5-dinitro­benzoic acid)rubidium]
title_full_unstemmed Poly[(μ-3,5-dinitro­benzoato)(μ-3,5-dinitro­benzoic acid)rubidium]
title_short Poly[(μ-3,5-dinitro­benzoato)(μ-3,5-dinitro­benzoic acid)rubidium]
title_sort poly[(μ-3,5-dinitro­benzoato)(μ-3,5-dinitro­benzoic acid)rubidium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212130/
https://www.ncbi.nlm.nih.gov/pubmed/22090832
http://dx.doi.org/10.1107/S160053681102513X
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