Aqua­(4-carb­oxy­pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))(1,10-phenanthroline-κ(2) N,N′)nickel(II)

The title compound, [Ni(C(8)H(3)NO(6))(C(12)H(8)N(2))(H(2)O)], contains an Ni(II) ion, a 1,10-phenanthroline (phen) ligand, a 4-carb­oxy­pyridine-2,6-dicarboxyl­ate (Hptc(2−)) anion and a coordinated water mol­ecule. The Ni(II) atom exhibits a distorted octa­hedral N(3)O(3) environment. O—H⋯O hydrog...

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Detalles Bibliográficos
Autores principales: Zou, Qin, Wang, Jian-fei, Lin, Jian-li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212132/
https://www.ncbi.nlm.nih.gov/pubmed/22090834
http://dx.doi.org/10.1107/S1600536811026055
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author Zou, Qin
Wang, Jian-fei
Lin, Jian-li
author_facet Zou, Qin
Wang, Jian-fei
Lin, Jian-li
author_sort Zou, Qin
collection PubMed
description The title compound, [Ni(C(8)H(3)NO(6))(C(12)H(8)N(2))(H(2)O)], contains an Ni(II) ion, a 1,10-phenanthroline (phen) ligand, a 4-carb­oxy­pyridine-2,6-dicarboxyl­ate (Hptc(2−)) anion and a coordinated water mol­ecule. The Ni(II) atom exhibits a distorted octa­hedral N(3)O(3) environment. O—H⋯O hydrogen bonding between coordinated water and carboxyl­ate O atoms, as well as π–π stacking inter­actions [inter­planar distances between phen rings = 3.293 (2) Å] lead to a supermolecular assembly.
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spelling pubmed-32121322011-11-16 Aqua­(4-carb­oxy­pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))(1,10-phenanthroline-κ(2) N,N′)nickel(II) Zou, Qin Wang, Jian-fei Lin, Jian-li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(8)H(3)NO(6))(C(12)H(8)N(2))(H(2)O)], contains an Ni(II) ion, a 1,10-phenanthroline (phen) ligand, a 4-carb­oxy­pyridine-2,6-dicarboxyl­ate (Hptc(2−)) anion and a coordinated water mol­ecule. The Ni(II) atom exhibits a distorted octa­hedral N(3)O(3) environment. O—H⋯O hydrogen bonding between coordinated water and carboxyl­ate O atoms, as well as π–π stacking inter­actions [inter­planar distances between phen rings = 3.293 (2) Å] lead to a supermolecular assembly. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212132/ /pubmed/22090834 http://dx.doi.org/10.1107/S1600536811026055 Text en © Zou et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zou, Qin
Wang, Jian-fei
Lin, Jian-li
Aqua­(4-carb­oxy­pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))(1,10-phenanthroline-κ(2) N,N′)nickel(II)
title Aqua­(4-carb­oxy­pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))(1,10-phenanthroline-κ(2) N,N′)nickel(II)
title_full Aqua­(4-carb­oxy­pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))(1,10-phenanthroline-κ(2) N,N′)nickel(II)
title_fullStr Aqua­(4-carb­oxy­pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))(1,10-phenanthroline-κ(2) N,N′)nickel(II)
title_full_unstemmed Aqua­(4-carb­oxy­pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))(1,10-phenanthroline-κ(2) N,N′)nickel(II)
title_short Aqua­(4-carb­oxy­pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))(1,10-phenanthroline-κ(2) N,N′)nickel(II)
title_sort aqua­(4-carb­oxy­pyridine-2,6-dicarboxyl­ato-κ(3) o (2),n,o (6))(1,10-phenanthroline-κ(2) n,n′)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212132/
https://www.ncbi.nlm.nih.gov/pubmed/22090834
http://dx.doi.org/10.1107/S1600536811026055
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AT wangjianfei aqua4carboxypyridine26dicarboxylatok3o2no6110phenanthrolinek2nnnickelii
AT linjianli aqua4carboxypyridine26dicarboxylatok3o2no6110phenanthrolinek2nnnickelii

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