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Aqua­chloridobis(2-{[3-(morpholin-4-yl)prop­yl]imino­meth­yl}phenolato)manganese(III) monohydrate

In the title compound, [Mn(C(14)H(19)N(2)O(2))(2)Cl(H(2)O)]·H(2)O, the Mn(III) atom is N,O-chelated by two monoanionic Schiff bases, forming two six-membered chelate rings. One Cl atom and one water mol­ecule in trans positions complete a distorted octa­hedral geometry around the metal atom. In the...

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Autores principales: Ikmal Hisham, Nurul Azimah, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212133/
https://www.ncbi.nlm.nih.gov/pubmed/22090835
http://dx.doi.org/10.1107/S1600536811026493
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author Ikmal Hisham, Nurul Azimah
Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Ikmal Hisham, Nurul Azimah
Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Ikmal Hisham, Nurul Azimah
collection PubMed
description In the title compound, [Mn(C(14)H(19)N(2)O(2))(2)Cl(H(2)O)]·H(2)O, the Mn(III) atom is N,O-chelated by two monoanionic Schiff bases, forming two six-membered chelate rings. One Cl atom and one water mol­ecule in trans positions complete a distorted octa­hedral geometry around the metal atom. In the crystal, the complex mol­ecules and the uncoordinated water mol­ecules are connected via O—H⋯N, O—H⋯O and O—H⋯Cl hydrogen bonds into layers parallel to the ac plane and these are consolidated by C—H⋯π inter­actions. The layers are further linked into a three-dimensional network through C—H⋯O inter­actions.
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spelling pubmed-32121332011-11-16 Aqua­chloridobis(2-{[3-(morpholin-4-yl)prop­yl]imino­meth­yl}phenolato)manganese(III) monohydrate Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(14)H(19)N(2)O(2))(2)Cl(H(2)O)]·H(2)O, the Mn(III) atom is N,O-chelated by two monoanionic Schiff bases, forming two six-membered chelate rings. One Cl atom and one water mol­ecule in trans positions complete a distorted octa­hedral geometry around the metal atom. In the crystal, the complex mol­ecules and the uncoordinated water mol­ecules are connected via O—H⋯N, O—H⋯O and O—H⋯Cl hydrogen bonds into layers parallel to the ac plane and these are consolidated by C—H⋯π inter­actions. The layers are further linked into a three-dimensional network through C—H⋯O inter­actions. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212133/ /pubmed/22090835 http://dx.doi.org/10.1107/S1600536811026493 Text en © Ikmal Hisham et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ikmal Hisham, Nurul Azimah
Khaledi, Hamid
Mohd Ali, Hapipah
Aqua­chloridobis(2-{[3-(morpholin-4-yl)prop­yl]imino­meth­yl}phenolato)manganese(III) monohydrate
title Aqua­chloridobis(2-{[3-(morpholin-4-yl)prop­yl]imino­meth­yl}phenolato)manganese(III) monohydrate
title_full Aqua­chloridobis(2-{[3-(morpholin-4-yl)prop­yl]imino­meth­yl}phenolato)manganese(III) monohydrate
title_fullStr Aqua­chloridobis(2-{[3-(morpholin-4-yl)prop­yl]imino­meth­yl}phenolato)manganese(III) monohydrate
title_full_unstemmed Aqua­chloridobis(2-{[3-(morpholin-4-yl)prop­yl]imino­meth­yl}phenolato)manganese(III) monohydrate
title_short Aqua­chloridobis(2-{[3-(morpholin-4-yl)prop­yl]imino­meth­yl}phenolato)manganese(III) monohydrate
title_sort aqua­chloridobis(2-{[3-(morpholin-4-yl)prop­yl]imino­meth­yl}phenolato)manganese(iii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212133/
https://www.ncbi.nlm.nih.gov/pubmed/22090835
http://dx.doi.org/10.1107/S1600536811026493
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