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Aquachloridobis(2-{[3-(morpholin-4-yl)propyl]iminomethyl}phenolato)manganese(III) monohydrate
In the title compound, [Mn(C(14)H(19)N(2)O(2))(2)Cl(H(2)O)]·H(2)O, the Mn(III) atom is N,O-chelated by two monoanionic Schiff bases, forming two six-membered chelate rings. One Cl atom and one water molecule in trans positions complete a distorted octahedral geometry around the metal atom. In the...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212133/ https://www.ncbi.nlm.nih.gov/pubmed/22090835 http://dx.doi.org/10.1107/S1600536811026493 |
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author | Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah |
author_facet | Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah |
author_sort | Ikmal Hisham, Nurul Azimah |
collection | PubMed |
description | In the title compound, [Mn(C(14)H(19)N(2)O(2))(2)Cl(H(2)O)]·H(2)O, the Mn(III) atom is N,O-chelated by two monoanionic Schiff bases, forming two six-membered chelate rings. One Cl atom and one water molecule in trans positions complete a distorted octahedral geometry around the metal atom. In the crystal, the complex molecules and the uncoordinated water molecules are connected via O—H⋯N, O—H⋯O and O—H⋯Cl hydrogen bonds into layers parallel to the ac plane and these are consolidated by C—H⋯π interactions. The layers are further linked into a three-dimensional network through C—H⋯O interactions. |
format | Online Article Text |
id | pubmed-3212133 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32121332011-11-16 Aquachloridobis(2-{[3-(morpholin-4-yl)propyl]iminomethyl}phenolato)manganese(III) monohydrate Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(14)H(19)N(2)O(2))(2)Cl(H(2)O)]·H(2)O, the Mn(III) atom is N,O-chelated by two monoanionic Schiff bases, forming two six-membered chelate rings. One Cl atom and one water molecule in trans positions complete a distorted octahedral geometry around the metal atom. In the crystal, the complex molecules and the uncoordinated water molecules are connected via O—H⋯N, O—H⋯O and O—H⋯Cl hydrogen bonds into layers parallel to the ac plane and these are consolidated by C—H⋯π interactions. The layers are further linked into a three-dimensional network through C—H⋯O interactions. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212133/ /pubmed/22090835 http://dx.doi.org/10.1107/S1600536811026493 Text en © Ikmal Hisham et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah Aquachloridobis(2-{[3-(morpholin-4-yl)propyl]iminomethyl}phenolato)manganese(III) monohydrate |
title | Aquachloridobis(2-{[3-(morpholin-4-yl)propyl]iminomethyl}phenolato)manganese(III) monohydrate |
title_full | Aquachloridobis(2-{[3-(morpholin-4-yl)propyl]iminomethyl}phenolato)manganese(III) monohydrate |
title_fullStr | Aquachloridobis(2-{[3-(morpholin-4-yl)propyl]iminomethyl}phenolato)manganese(III) monohydrate |
title_full_unstemmed | Aquachloridobis(2-{[3-(morpholin-4-yl)propyl]iminomethyl}phenolato)manganese(III) monohydrate |
title_short | Aquachloridobis(2-{[3-(morpholin-4-yl)propyl]iminomethyl}phenolato)manganese(III) monohydrate |
title_sort | aquachloridobis(2-{[3-(morpholin-4-yl)propyl]iminomethyl}phenolato)manganese(iii) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212133/ https://www.ncbi.nlm.nih.gov/pubmed/22090835 http://dx.doi.org/10.1107/S1600536811026493 |
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