N,N′-Dimethyl­ethylenediammonium dioxalatocuprate(II)

The asymmetric unit of the title salt, (C(4)H(14)N(2))[Cu(C(2)O(4))(2)], consists of one complex anion and two cationic half-mol­ecules, the other halves being generated by inversion symmetry. The Cu(II) atom in the anion is coordinated by two bidentate oxalate ligands in a distorted square-planar g...

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Autores principales: Gaye, Papa Aly, Sarr, Aminata Diassé, Gaye, Mohamed, Sanselme, Morgane, Agasse, Peulon Valérie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212134/
https://www.ncbi.nlm.nih.gov/pubmed/22090836
http://dx.doi.org/10.1107/S1600536811025682
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author Gaye, Papa Aly
Sarr, Aminata Diassé
Gaye, Mohamed
Sanselme, Morgane
Agasse, Peulon Valérie
author_facet Gaye, Papa Aly
Sarr, Aminata Diassé
Gaye, Mohamed
Sanselme, Morgane
Agasse, Peulon Valérie
author_sort Gaye, Papa Aly
collection PubMed
description The asymmetric unit of the title salt, (C(4)H(14)N(2))[Cu(C(2)O(4))(2)], consists of one complex anion and two cationic half-mol­ecules, the other halves being generated by inversion symmetry. The Cu(II) atom in the anion is coordinated by two bidentate oxalate ligands in a distorted square-planar geometry. Inter­molecular hydrogen bonds, involving the NH groups as donors and O atoms as acceptors, are observed, which lead to the formation of a three-dimensional network structure.
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spelling pubmed-32121342011-11-16 N,N′-Dimethyl­ethylenediammonium dioxalatocuprate(II) Gaye, Papa Aly Sarr, Aminata Diassé Gaye, Mohamed Sanselme, Morgane Agasse, Peulon Valérie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title salt, (C(4)H(14)N(2))[Cu(C(2)O(4))(2)], consists of one complex anion and two cationic half-mol­ecules, the other halves being generated by inversion symmetry. The Cu(II) atom in the anion is coordinated by two bidentate oxalate ligands in a distorted square-planar geometry. Inter­molecular hydrogen bonds, involving the NH groups as donors and O atoms as acceptors, are observed, which lead to the formation of a three-dimensional network structure. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212134/ /pubmed/22090836 http://dx.doi.org/10.1107/S1600536811025682 Text en © Gaye et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gaye, Papa Aly
Sarr, Aminata Diassé
Gaye, Mohamed
Sanselme, Morgane
Agasse, Peulon Valérie
N,N′-Dimethyl­ethylenediammonium dioxalatocuprate(II)
title N,N′-Dimethyl­ethylenediammonium dioxalatocuprate(II)
title_full N,N′-Dimethyl­ethylenediammonium dioxalatocuprate(II)
title_fullStr N,N′-Dimethyl­ethylenediammonium dioxalatocuprate(II)
title_full_unstemmed N,N′-Dimethyl­ethylenediammonium dioxalatocuprate(II)
title_short N,N′-Dimethyl­ethylenediammonium dioxalatocuprate(II)
title_sort n,n′-dimethyl­ethylenediammonium dioxalatocuprate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212134/
https://www.ncbi.nlm.nih.gov/pubmed/22090836
http://dx.doi.org/10.1107/S1600536811025682
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