Bis(2-amino­pyrazine-κN (4))dichlorido­zinc

In the title adduct, [ZnCl(2)(C(4)H(5)N(3))(2)], the Zn(II) atom lies on a twofold rotation axis that relates one Cl atom to the other as well as one 2-amino­pyrazine ligand to the other; the coordination geometry is a distorted tetra­hedron. In the crystal, adjacent mol­ecules are linked by N—H⋯N h...

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Detalles Bibliográficos
Autores principales: Gao, Shan, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212136/
https://www.ncbi.nlm.nih.gov/pubmed/22090838
http://dx.doi.org/10.1107/S1600536811026031
Descripción
Sumario:In the title adduct, [ZnCl(2)(C(4)H(5)N(3))(2)], the Zn(II) atom lies on a twofold rotation axis that relates one Cl atom to the other as well as one 2-amino­pyrazine ligand to the other; the coordination geometry is a distorted tetra­hedron. In the crystal, adjacent mol­ecules are linked by N—H⋯N hydrogen bonds across the center of inversion, generating a chain; neighboring chains are linked by N—H⋯Cl hydrogen bonds, forming a three-dimensional network.

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