Bis(2-amino­pyrazine-κN (4))dichlorido­zinc

In the title adduct, [ZnCl(2)(C(4)H(5)N(3))(2)], the Zn(II) atom lies on a twofold rotation axis that relates one Cl atom to the other as well as one 2-amino­pyrazine ligand to the other; the coordination geometry is a distorted tetra­hedron. In the crystal, adjacent mol­ecules are linked by N—H⋯N h...

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Detalles Bibliográficos
Autores principales: Gao, Shan, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212136/
https://www.ncbi.nlm.nih.gov/pubmed/22090838
http://dx.doi.org/10.1107/S1600536811026031
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author Gao, Shan
Ng, Seik Weng
author_facet Gao, Shan
Ng, Seik Weng
author_sort Gao, Shan
collection PubMed
description In the title adduct, [ZnCl(2)(C(4)H(5)N(3))(2)], the Zn(II) atom lies on a twofold rotation axis that relates one Cl atom to the other as well as one 2-amino­pyrazine ligand to the other; the coordination geometry is a distorted tetra­hedron. In the crystal, adjacent mol­ecules are linked by N—H⋯N hydrogen bonds across the center of inversion, generating a chain; neighboring chains are linked by N—H⋯Cl hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-32121362011-11-16 Bis(2-amino­pyrazine-κN (4))dichlorido­zinc Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title adduct, [ZnCl(2)(C(4)H(5)N(3))(2)], the Zn(II) atom lies on a twofold rotation axis that relates one Cl atom to the other as well as one 2-amino­pyrazine ligand to the other; the coordination geometry is a distorted tetra­hedron. In the crystal, adjacent mol­ecules are linked by N—H⋯N hydrogen bonds across the center of inversion, generating a chain; neighboring chains are linked by N—H⋯Cl hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212136/ /pubmed/22090838 http://dx.doi.org/10.1107/S1600536811026031 Text en © Gao and Ng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Shan
Ng, Seik Weng
Bis(2-amino­pyrazine-κN (4))dichlorido­zinc
title Bis(2-amino­pyrazine-κN (4))dichlorido­zinc
title_full Bis(2-amino­pyrazine-κN (4))dichlorido­zinc
title_fullStr Bis(2-amino­pyrazine-κN (4))dichlorido­zinc
title_full_unstemmed Bis(2-amino­pyrazine-κN (4))dichlorido­zinc
title_short Bis(2-amino­pyrazine-κN (4))dichlorido­zinc
title_sort bis(2-amino­pyrazine-κn (4))dichlorido­zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212136/
https://www.ncbi.nlm.nih.gov/pubmed/22090838
http://dx.doi.org/10.1107/S1600536811026031
work_keys_str_mv AT gaoshan bis2aminopyrazinekn4dichloridozinc
AT ngseikweng bis2aminopyrazinekn4dichloridozinc

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