catena-Poly[[[dichloridomercury(II)]-μ-1,4-bis­(3-pyridyl­amino­meth­yl)benzene-κ(2) N:N′] N,N-dimethyl­formamide monosolvate]

The crystal structure of the polymeric title compound, {[HgCl(2)(C(18)H(18)N(4))]·C(3)H(7)NO}(n), features an N-heterocyclic ligand which links adjacent HgCl(2) units into a helical chain running along the b axis. The coordination geometry of the Hg(II) atom is a distorted tetra­hedron. The dimethyl...

Descripción completa

Detalles Bibliográficos
Autores principales: Gao, Shan, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212137/
https://www.ncbi.nlm.nih.gov/pubmed/22090839
http://dx.doi.org/10.1107/S1600536811026043
_version_ 1782215926805954560
author Gao, Shan
Ng, Seik Weng
author_facet Gao, Shan
Ng, Seik Weng
author_sort Gao, Shan
collection PubMed
description The crystal structure of the polymeric title compound, {[HgCl(2)(C(18)H(18)N(4))]·C(3)H(7)NO}(n), features an N-heterocyclic ligand which links adjacent HgCl(2) units into a helical chain running along the b axis. The coordination geometry of the Hg(II) atom is a distorted tetra­hedron. The dimethyl­formamide mol­ecule is disordered over two positions in a 1:1 ratio, and is linked to the complex mol­ecules via N—H⋯O hydrogen bonds.
format Online
Article
Text
id pubmed-3212137
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32121372011-11-16 catena-Poly[[[dichloridomercury(II)]-μ-1,4-bis­(3-pyridyl­amino­meth­yl)benzene-κ(2) N:N′] N,N-dimethyl­formamide monosolvate] Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the polymeric title compound, {[HgCl(2)(C(18)H(18)N(4))]·C(3)H(7)NO}(n), features an N-heterocyclic ligand which links adjacent HgCl(2) units into a helical chain running along the b axis. The coordination geometry of the Hg(II) atom is a distorted tetra­hedron. The dimethyl­formamide mol­ecule is disordered over two positions in a 1:1 ratio, and is linked to the complex mol­ecules via N—H⋯O hydrogen bonds. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212137/ /pubmed/22090839 http://dx.doi.org/10.1107/S1600536811026043 Text en © Gao and Ng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Shan
Ng, Seik Weng
catena-Poly[[[dichloridomercury(II)]-μ-1,4-bis­(3-pyridyl­amino­meth­yl)benzene-κ(2) N:N′] N,N-dimethyl­formamide monosolvate]
title catena-Poly[[[dichloridomercury(II)]-μ-1,4-bis­(3-pyridyl­amino­meth­yl)benzene-κ(2) N:N′] N,N-dimethyl­formamide monosolvate]
title_full catena-Poly[[[dichloridomercury(II)]-μ-1,4-bis­(3-pyridyl­amino­meth­yl)benzene-κ(2) N:N′] N,N-dimethyl­formamide monosolvate]
title_fullStr catena-Poly[[[dichloridomercury(II)]-μ-1,4-bis­(3-pyridyl­amino­meth­yl)benzene-κ(2) N:N′] N,N-dimethyl­formamide monosolvate]
title_full_unstemmed catena-Poly[[[dichloridomercury(II)]-μ-1,4-bis­(3-pyridyl­amino­meth­yl)benzene-κ(2) N:N′] N,N-dimethyl­formamide monosolvate]
title_short catena-Poly[[[dichloridomercury(II)]-μ-1,4-bis­(3-pyridyl­amino­meth­yl)benzene-κ(2) N:N′] N,N-dimethyl­formamide monosolvate]
title_sort catena-poly[[[dichloridomercury(ii)]-μ-1,4-bis­(3-pyridyl­amino­meth­yl)benzene-κ(2) n:n′] n,n-dimethyl­formamide monosolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212137/
https://www.ncbi.nlm.nih.gov/pubmed/22090839
http://dx.doi.org/10.1107/S1600536811026043
work_keys_str_mv AT gaoshan catenapolydichloridomercuryiim14bis3pyridylaminomethylbenzenek2nnnndimethylformamidemonosolvate
AT ngseikweng catenapolydichloridomercuryiim14bis3pyridylaminomethylbenzenek2nnnndimethylformamidemonosolvate

Ejemplares similares