Bis(4-methyl­morpholin-4-ium) tetra­bromidozincate(II)

The title compound, (C(5)H(12)NO)(2)[ZnBr(4)], was synthesized by hydro­thermal reaction of ZnBr(2) with 4-methyl­morpholine in a HBr/distilled water solution. Each of the two independent cations exhibits a chair conformation; the anion deviates slightly from an tetrahedral configuration. The Zn—Br...

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Detalles Bibliográficos
Autores principales: Peng, Cong-hu, Li, Yun-peng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212140/
https://www.ncbi.nlm.nih.gov/pubmed/22090842
http://dx.doi.org/10.1107/S1600536811026766
Descripción
Sumario:The title compound, (C(5)H(12)NO)(2)[ZnBr(4)], was synthesized by hydro­thermal reaction of ZnBr(2) with 4-methyl­morpholine in a HBr/distilled water solution. Each of the two independent cations exhibits a chair conformation; the anion deviates slightly from an tetrahedral configuration. The Zn—Br distances in the anion are in the range of 2.3996 (9)–2.4247 (9) Å. All of the amine H atoms are involved in bifurcated inter­molecular N—H⋯Br hydrogen bonds, building up a trimer.

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