Bis(4-methyl­morpholin-4-ium) tetra­bromidozincate(II)

The title compound, (C(5)H(12)NO)(2)[ZnBr(4)], was synthesized by hydro­thermal reaction of ZnBr(2) with 4-methyl­morpholine in a HBr/distilled water solution. Each of the two independent cations exhibits a chair conformation; the anion deviates slightly from an tetrahedral configuration. The Zn—Br...

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Detalles Bibliográficos
Autores principales: Peng, Cong-hu, Li, Yun-peng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212140/
https://www.ncbi.nlm.nih.gov/pubmed/22090842
http://dx.doi.org/10.1107/S1600536811026766
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author Peng, Cong-hu
Li, Yun-peng
author_facet Peng, Cong-hu
Li, Yun-peng
author_sort Peng, Cong-hu
collection PubMed
description The title compound, (C(5)H(12)NO)(2)[ZnBr(4)], was synthesized by hydro­thermal reaction of ZnBr(2) with 4-methyl­morpholine in a HBr/distilled water solution. Each of the two independent cations exhibits a chair conformation; the anion deviates slightly from an tetrahedral configuration. The Zn—Br distances in the anion are in the range of 2.3996 (9)–2.4247 (9) Å. All of the amine H atoms are involved in bifurcated inter­molecular N—H⋯Br hydrogen bonds, building up a trimer.
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spelling pubmed-32121402011-11-16 Bis(4-methyl­morpholin-4-ium) tetra­bromidozincate(II) Peng, Cong-hu Li, Yun-peng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(5)H(12)NO)(2)[ZnBr(4)], was synthesized by hydro­thermal reaction of ZnBr(2) with 4-methyl­morpholine in a HBr/distilled water solution. Each of the two independent cations exhibits a chair conformation; the anion deviates slightly from an tetrahedral configuration. The Zn—Br distances in the anion are in the range of 2.3996 (9)–2.4247 (9) Å. All of the amine H atoms are involved in bifurcated inter­molecular N—H⋯Br hydrogen bonds, building up a trimer. International Union of Crystallography 2011-07-09 /pmc/articles/PMC3212140/ /pubmed/22090842 http://dx.doi.org/10.1107/S1600536811026766 Text en © Peng and Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Peng, Cong-hu
Li, Yun-peng
Bis(4-methyl­morpholin-4-ium) tetra­bromidozincate(II)
title Bis(4-methyl­morpholin-4-ium) tetra­bromidozincate(II)
title_full Bis(4-methyl­morpholin-4-ium) tetra­bromidozincate(II)
title_fullStr Bis(4-methyl­morpholin-4-ium) tetra­bromidozincate(II)
title_full_unstemmed Bis(4-methyl­morpholin-4-ium) tetra­bromidozincate(II)
title_short Bis(4-methyl­morpholin-4-ium) tetra­bromidozincate(II)
title_sort bis(4-methyl­morpholin-4-ium) tetra­bromidozincate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212140/
https://www.ncbi.nlm.nih.gov/pubmed/22090842
http://dx.doi.org/10.1107/S1600536811026766
work_keys_str_mv AT pengconghu bis4methylmorpholin4iumtetrabromidozincateii
AT liyunpeng bis4methylmorpholin4iumtetrabromidozincateii

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